tert-Butyl-((E)-6-[1,3]dioxolan-2-yl-3-methyl-hex-2-enyloxy)-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-((E)-6-[1,3]dioxolan-2-yl-3-methyl-hex-2-enyloxy)-diphenyl-silane
CAS No.:181651-54-7
Molecular Formula:C₂₆H₃₆O₃Si
Molecular Weight:424.656
Hs Code.:

Synonyms:tert-Butyl-((E)-6-[1,3]dioxolan-2-yl-3-methyl-hex-2-enyloxy)-diphenyl-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-Butyl-((E)-6-[1,3]dioxolan-2-yl-3-methyl-hex-2-enyloxy)-diphenyl-silane

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Technology Process of tert-Butyl-((E)-6-[1,3]dioxolan-2-yl-3-methyl-hex-2-enyloxy)-diphenyl-silane

There total 1 articles about tert-Butyl-((E)-6-[1,3]dioxolan-2-yl-3-methyl-hex-2-enyloxy)-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 107-21-1
ethylene glycol

: tert-Butyl-((2E,6E)-7-methoxy-3-methyl-hepta-2,6-dienyloxy)-diphenyl-silane

: 181651-54-7
tert-Butyl-((E)-6-[1,3]dioxolan-2-yl-3-methyl-hex-2-enyloxy)-diphenyl-silane

Guidance literature:: With toluene-4-sulfonic acid; In benzene; for 5h; Heating;
DOI:10.1021/jo960924y

Reference yield:

: 181651-54-7
tert-Butyl-((E)-6-[1,3]dioxolan-2-yl-3-methyl-hex-2-enyloxy)-diphenyl-silane

: 181651-51-4
N-Cyclohex-1-enyl-N-((E)-3-methyl-7-oxo-hept-2-enyl)-acetamide

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / TBAF / tetrahydrofuran / 3 h / 0 - 20 °C

2: 86 percent / PPh₃, DIAD / tetrahydrofuran / 6 h / Ambient temperature

3: 91 percent / MeNH₂ / ethanol / 7 h / Heating

4: 1) K₂CO₃, 2) pyridine / 1) benzene, reflux, 15 h, 2) benzene, room temperature, 20 min

5: 38 percent / pyridinium p-toluenesulfonate / acetone; H₂O / 7 h / Heating

With pyridine; di-isopropyl azodicarboxylate; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; potassium carbonate; triphenylphosphine; methylamine; In tetrahydrofuran; ethanol; water; acetone;
DOI:10.1021/jo960924y

Reference yield:

: 181651-54-7
tert-Butyl-((E)-6-[1,3]dioxolan-2-yl-3-methyl-hex-2-enyloxy)-diphenyl-silane

: 181651-50-3
N-Cyclohex-1-enyl-N-((E)-6-[1,3]dioxolan-2-yl-3-methyl-hex-2-enyl)-acetamide

Guidance literature:: Multi-step reaction with 4 steps

1: 95 percent / TBAF / tetrahydrofuran / 3 h / 0 - 20 °C

2: 86 percent / PPh₃, DIAD / tetrahydrofuran / 6 h / Ambient temperature

3: 91 percent / MeNH₂ / ethanol / 7 h / Heating

4: 1) K₂CO₃, 2) pyridine / 1) benzene, reflux, 15 h, 2) benzene, room temperature, 20 min

With pyridine; di-isopropyl azodicarboxylate; tetrabutyl ammonium fluoride; potassium carbonate; triphenylphosphine; methylamine; In tetrahydrofuran; ethanol;
DOI:10.1021/jo960924y