methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate-(1->4)-1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-4-O-β-D-glucopyranose

Base Information

Chemical Name:methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate-(1->4)-1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-4-O-β-D-glucopyranose
CAS No.:247077-97-0
Molecular Formula:C₃₀H₃₇N₃O₁₆
Molecular Weight:695.634
Hs Code.:

Synonyms:methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate-(1->4)-1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-4-O-β-D-glucopyranose

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Chemical Property of methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate-(1->4)-1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-4-O-β-D-glucopyranose

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Technology Process of methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate-(1->4)-1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-4-O-β-D-glucopyranose

There total 1 articles about methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate-(1->4)-1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-4-O-β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 175978-92-4
1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranose

: methyl 2,3,4-tri-O-acetyl-α,β-D-glucopyranosyluronate trichloroacetimidate

: 247077-97-0
methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate-(1->4)-1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-4-O-β-D-glucopyranose

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; In dichloromethane; at -20 ℃; for 4h;
DOI:10.1016/S0968-0896(99)00106-6

Reference yield:

: 247077-97-0
methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate-(1->4)-1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-4-O-β-D-glucopyranose

: 6-O-acetyl-2-azido-3-O-benzyl-2-deoxy-4-O-(methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate)-D-glucopyranose

Guidance literature:: With benzylamine; In diethyl ether; at 0 ℃; for 1h;
DOI:10.1016/S0968-0896(99)00106-6

Reference yield:

: 247077-97-0
methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate-(1->4)-1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-4-O-β-D-glucopyranose

: 247077-99-2
(2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-[(2R,3S,4R,5R)-2-acetoxymethyl-5-azido-4-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-2-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: benzylamine / diethyl ether / 1 h / 0 °C

2: 148 mg / 4 Angstroem molecular sieves; potassium carbonate / CH₂Cl₂

With 4 A molecular sieve; potassium carbonate; benzylamine; In diethyl ether; dichloromethane; 1: Deacetylation / 2: Addition;
DOI:10.1016/S0968-0896(99)00106-6