2-[(8-Chloro-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluorooctyl)oxy]-1,1,2,2-tetrafluoroethanesulfonyl fluoride

Base Information

• Chemical Name: 2-[(8-Chloro-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluorooctyl)oxy]-1,1,2,2-tetrafluoroethanesulfonyl fluoride
• CAS No.: 73606-15-2
• Molecular Formula: C₁₀ClF₂₁O₃S
• Molecular Weight: 634.594
• DSSTox Substance ID: DTXSID80510950
• Nikkaji Number: J3.273.805B
• Wikidata: Q82369528
• Mol file: 73606-15-2.mol

Synonyms:73606-15-2;2-[(8-CHLORO-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-HEXADECAFLUOROOCTYL)OXY]-1,1,2,2-TETRAFLUOROETHANESULFONYL FLUORIDE;Ethanesulfonylfluoride,2-[(8-chloro-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluorooctyl)oxy]-1,1,2,2-tetrafluoro-;11-chloroperfluoro-3-oxaundecanesulfonyl fluoride;2-(8-chloro-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluorooctoxy)-1,1,2,2-tetrafluoroethanesulfonyl fluoride;DTXSID80510950;FT-0765773;NS00019226;2-(8-Chloroperfluorooctyloxy)tetrafluoroethanesulfonyl Fluoride (Technical Grade);2-(8-chloro-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluorooctyloxy)-1,1,2,2-tetrafluoroethanesulfonyl fluoride

Chemical Property of 2-[(8-Chloro-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluorooctyl)oxy]-1,1,2,2-tetrafluoroethanesulfonyl fluoride

Chemical Property:

• Boiling Point: 261.0±40.0 °C(Predicted)
• PSA: 51.75000
• Density: 1.827±0.06 g/cm3(Predicted)
• LogP: 7.80490
• Storage Temp.: Hygroscopic, Refrigerator, under inert atmosphere
• XLogP3: 7.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 24
• Rotatable Bond Count: 11
• Exact Mass: 633.8921341
• Heavy Atom Count: 36
• Complexity: 934

Purity/Quality:

99% ^*data from raw suppliers

2-[(8-CHLORO-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-HEXADECAFLUOROOCTYL)OXY]-1,1,2,2-TETRAFLUOROETHANESULFONYL FLUORIDE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(C(C(F)(F)Cl)(F)F)(F)F)(F)F)(C(C(C(OC(C(F)(F)S(=O)(=O)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of 2-[(8-Chloro-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluorooctyl)oxy]-1,1,2,2-tetrafluoroethanesulfonyl fluoride

There total 2 articles about 2-[(8-Chloro-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluorooctyl)oxy]-1,1,2,2-tetrafluoroethanesulfonyl fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

chloroperfluoro-1-hexene (31001-56-6) + 1,1,2,2-tetrafluoroethanesulfonyl fluoride (82106-27-2) → 3-oxa-11-chloroperfluoro-undecane sulfonylfluoride (73606-15-2)

Guidance literature:

With potassium fluoride; chlorine; In diethylene glycol dimethyl ether; 1) 10 min, 2) 40 deg C, 6 h;

DOI:10.1021/jo00022a025

Reference yield:

1,1,2,2-Tetrafluoro-2-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluoro-8-iodo-octyloxy)-ethanesulfonyl fluoride (68136-90-3) + chlorine (7782-50-5) → 3-oxa-11-chloroperfluoro-undecane sulfonylfluoride (73606-15-2)

Guidance literature:

180-200°C;

upstream raw materials:

chloroperfluoro-1-hexene

1,1,2,2-tetrafluoroethanesulfonyl fluoride

1,1,2,2-Tetrafluoro-2-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluoro-8-iodo-octyloxy)-ethanesulfonyl fluoride

chlorine

Refernces