dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleninyl)-4-hydroxycyclohex-5-ene-1-carboxylate

Base Information

Chemical Name:dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleninyl)-4-hydroxycyclohex-5-ene-1-carboxylate
CAS No.:472994-08-4
Molecular Formula:C₁₉H₂₂O₆Se
Molecular Weight:425.34
Hs Code.:

Synonyms:dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleninyl)-4-hydroxycyclohex-5-ene-1-carboxylate

Suppliers and Price of dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleninyl)-4-hydroxycyclohex-5-ene-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleninyl)-4-hydroxycyclohex-5-ene-1-carboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleninyl)-4-hydroxycyclohex-5-ene-1-carboxylate

There total 3 articles about dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleninyl)-4-hydroxycyclohex-5-ene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 472993-94-5
dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleno)-4-hydroxycyclohex-5-ene-1-carboxylate

: 472994-08-4
dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleninyl)-4-hydroxycyclohex-5-ene-1-carboxylate

Guidance literature:: With dihydrogen peroxide; In tetrahydrofuran; dichloromethane; at 5 ℃; for 2.5h;
DOI:10.1021/ja00238a029

Reference yield:

: 5707-04-0
Phenylselenyl chloride

: 472994-08-4
dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleninyl)-4-hydroxycyclohex-5-ene-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) AgOOCCF₃, 2) K₂CO₃ / 1) CH₂Cl₂, -78 deg C, 15 min, 2) CH₂Cl₂, RT, 5 h

2: 95 percent / 30percent H₂O₂ / CH₂Cl₂; tetrahydrofuran / 2.5 h / 5 °C

With dihydrogen peroxide; silver trifluoroacetate; potassium carbonate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00238a029

Reference yield:

: 106094-16-0
dimethyl 1-<2-carboxylato-2-propenyl>-1,2-dihydrobenzoate

: 472994-08-4
dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleninyl)-4-hydroxycyclohex-5-ene-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) AgOOCCF₃, 2) K₂CO₃ / 1) CH₂Cl₂, -78 deg C, 15 min, 2) CH₂Cl₂, RT, 5 h

2: 95 percent / 30percent H₂O₂ / CH₂Cl₂; tetrahydrofuran / 2.5 h / 5 °C

With dihydrogen peroxide; silver trifluoroacetate; potassium carbonate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00238a029