(E/Z)-4-methoxy-1-({4-[5-methyl-3-(2-methylpropyl)hexylidene]-2-[(phenylmethoxy)methyl](2-2,3,5-trihydrofuryl)}methoxy)benzene

Base Information

Chemical Name:(E/Z)-4-methoxy-1-({4-[5-methyl-3-(2-methylpropyl)hexylidene]-2-[(phenylmethoxy)methyl](2-2,3,5-trihydrofuryl)}methoxy)benzene
CAS No.:862549-16-4
Molecular Formula:C₃₁H₄₄O₄
Molecular Weight:480.688
Hs Code.:

Synonyms:(E/Z)-4-methoxy-1-({4-[5-methyl-3-(2-methylpropyl)hexylidene]-2-[(phenylmethoxy)methyl](2-2,3,5-trihydrofuryl)}methoxy)benzene

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Chemical Property of (E/Z)-4-methoxy-1-({4-[5-methyl-3-(2-methylpropyl)hexylidene]-2-[(phenylmethoxy)methyl](2-2,3,5-trihydrofuryl)}methoxy)benzene

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Technology Process of (E/Z)-4-methoxy-1-({4-[5-methyl-3-(2-methylpropyl)hexylidene]-2-[(phenylmethoxy)methyl](2-2,3,5-trihydrofuryl)}methoxy)benzene

There total 7 articles about (E/Z)-4-methoxy-1-({4-[5-methyl-3-(2-methylpropyl)hexylidene]-2-[(phenylmethoxy)methyl](2-2,3,5-trihydrofuryl)}methoxy)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: [5-methyl-3-(2-methylpropyl)hexyl]triphenylphosphonium iodide

: 249930-10-7
5-{[(4-methoxyphenyl)methoxy]methyl}-5-[(phenylmethoxy)methyl]oxolan-3-one

: 862549-16-4
(E/Z)-4-methoxy-1-({4-[5-methyl-3-(2-methylpropyl)hexylidene]-2-[(phenylmethoxy)methyl](2-2,3,5-trihydrofuryl)}methoxy)benzene

Guidance literature:: [5-methyl-3-(2-methylpropyl)hexyl]triphenylphosphonium iodide; With n-butyllithium; In tetrahydrofuran; at 20 ℃; for 0.5h;

5-{[(4-methoxyphenyl)methoxy]methyl}-5-[(phenylmethoxy)methyl]oxolan-3-one; In tetrahydrofuran; for 2h; Heating;
DOI:10.1021/jm050352m

Reference yield:

: 108-83-8
diisobutyl ketone

: 862549-16-4
(E/Z)-4-methoxy-1-({4-[5-methyl-3-(2-methylpropyl)hexylidene]-2-[(phenylmethoxy)methyl](2-2,3,5-trihydrofuryl)}methoxy)benzene

Guidance literature:: Multi-step reaction with 7 steps

1.1: 92 percent / tetrahydrofuran / -78 - 20 °C

2.1: 95 percent / PCC; molecular sieves 4 Angstroem / CH₂Cl₂ / 24 h / 20 °C

3.1: 64 percent / H₂ / Pd/C / CH₂Cl₂ / 3 h / 20 °C

4.1: 83 percent / LiAlH₄ / tetrahydrofuran / 0 °C

5.1: 78 percent / triphenylphosphine; imidazole; I₂ / tetrahydrofuran / 2 h / 20 °C

6.1: 84 percent / toluene / 24 h / Heating

7.1: n-butyllithium / tetrahydrofuran / 0.5 h / 20 °C

7.2: 40 percent / tetrahydrofuran / 2 h / Heating

With 1H-imidazole; lithium aluminium tetrahydride; n-butyllithium; 4 A molecular sieve; hydrogen; iodine; triphenylphosphine; pyridinium chlorochromate; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/jm050352m

Reference yield:

: 585538-79-0
5-methyl-3-(2-methylpropyl)hex-2-en-1-one

: 862549-16-4
(E/Z)-4-methoxy-1-({4-[5-methyl-3-(2-methylpropyl)hexylidene]-2-[(phenylmethoxy)methyl](2-2,3,5-trihydrofuryl)}methoxy)benzene

Guidance literature:: Multi-step reaction with 5 steps

1.1: 64 percent / H₂ / Pd/C / CH₂Cl₂ / 3 h / 20 °C

2.1: 83 percent / LiAlH₄ / tetrahydrofuran / 0 °C

3.1: 78 percent / triphenylphosphine; imidazole; I₂ / tetrahydrofuran / 2 h / 20 °C

4.1: 84 percent / toluene / 24 h / Heating

5.1: n-butyllithium / tetrahydrofuran / 0.5 h / 20 °C

5.2: 40 percent / tetrahydrofuran / 2 h / Heating

With 1H-imidazole; lithium aluminium tetrahydride; n-butyllithium; hydrogen; iodine; triphenylphosphine; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/jm050352m