tert-butyl 3-methoxy-4-(2-nitro-3-(triisopropylsilyloxy)propyl)phenyl carbonate

Base Information

Chemical Name:tert-butyl 3-methoxy-4-(2-nitro-3-(triisopropylsilyloxy)propyl)phenyl carbonate
CAS No.:950487-15-7
Molecular Formula:C₂₄H₄₁NO₇Si
Molecular Weight:483.678
Hs Code.:

Synonyms:tert-butyl 3-methoxy-4-(2-nitro-3-(triisopropylsilyloxy)propyl)phenyl carbonate

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Chemical Property of tert-butyl 3-methoxy-4-(2-nitro-3-(triisopropylsilyloxy)propyl)phenyl carbonate

Chemical Property:

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Technology Process of tert-butyl 3-methoxy-4-(2-nitro-3-(triisopropylsilyloxy)propyl)phenyl carbonate

There total 3 articles about tert-butyl 3-methoxy-4-(2-nitro-3-(triisopropylsilyloxy)propyl)phenyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 950487-13-5
tert-butyl 3-hydroxy-4-(2-nitro-3-(triisopropylsilyloxy)propyl)phenyl carbonate

: 950487-15-7
tert-butyl 3-methoxy-4-(2-nitro-3-(triisopropylsilyloxy)propyl)phenyl carbonate

Guidance literature:: In diethyl ether; for 8h;
DOI:10.1021/ol0710257

Reference yield:

: 288268-32-6
bis-(2,4-tert-butoxycarbonyloxy)-benzaldehyde

: 950487-15-7
tert-butyl 3-methoxy-4-(2-nitro-3-(triisopropylsilyloxy)propyl)phenyl carbonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: t-BuONa / tetrahydrofuran / 0 °C

1.2: tetrahydrofuran / -78 - 0 °C

1.3: 49 percent / NaBH₄ / tetrahydrofuran; H₂O / 0.42 h

2.1: 55 percent / diethyl ether / 8 h

With sodium t-butanolate; In tetrahydrofuran; diethyl ether;
DOI:10.1021/ol0710257

Reference yield:

: 482580-72-3
3-nitro-O-triisopropylsilyl-1-ethanol

: 950487-15-7
tert-butyl 3-methoxy-4-(2-nitro-3-(triisopropylsilyloxy)propyl)phenyl carbonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: t-BuONa / tetrahydrofuran / 0 °C

1.2: tetrahydrofuran / -78 - 0 °C

1.3: 49 percent / NaBH₄ / tetrahydrofuran; H₂O / 0.42 h

2.1: 55 percent / diethyl ether / 8 h

With sodium t-butanolate; In tetrahydrofuran; diethyl ether;
DOI:10.1021/ol0710257