tert-Butyl-{(E)-3-[2-((E)-5-chloro-4-fluoro-pent-3-enyl)-4-methoxy-phenyl]-allyloxy}-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-{(E)-3-[2-((E)-5-chloro-4-fluoro-pent-3-enyl)-4-methoxy-phenyl]-allyloxy}-diphenyl-silane
CAS No.:853061-31-1
Molecular Formula:C₃₁H₃₆ClFO₂Si
Molecular Weight:523.163
Hs Code.:

Synonyms:tert-Butyl-{(E)-3-[2-((E)-5-chloro-4-fluoro-pent-3-enyl)-4-methoxy-phenyl]-allyloxy}-diphenyl-silane

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Chemical Property of tert-Butyl-{(E)-3-[2-((E)-5-chloro-4-fluoro-pent-3-enyl)-4-methoxy-phenyl]-allyloxy}-diphenyl-silane

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Technology Process of tert-Butyl-{(E)-3-[2-((E)-5-chloro-4-fluoro-pent-3-enyl)-4-methoxy-phenyl]-allyloxy}-diphenyl-silane

There total 13 articles about tert-Butyl-{(E)-3-[2-((E)-5-chloro-4-fluoro-pent-3-enyl)-4-methoxy-phenyl]-allyloxy}-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 853061-30-0
(E)-5-{2-[(E)-3-(tert-Butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-2-fluoro-pent-2-en-1-ol

: 853061-31-1
tert-Butyl-{(E)-3-[2-((E)-5-chloro-4-fluoro-pent-3-enyl)-4-methoxy-phenyl]-allyloxy}-diphenyl-silane

Guidance literature:: With 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine; In tetrahydrofuran; at -40 ℃; for 0.333333h;
DOI:10.1139/v05-259

Reference yield:

: 853061-12-8
2-(3-hydroxy-propyl)-4-methoxy-benzaldehyde

: 853061-31-1
tert-Butyl-{(E)-3-[2-((E)-5-chloro-4-fluoro-pent-3-enyl)-4-methoxy-phenyl]-allyloxy}-diphenyl-silane

Guidance literature:: Multi-step reaction with 9 steps

1: 100 percent / imidazole / tetrahydrofuran / 0.75 h / 20 °C

2: 97 percent / sodium hydride / tetrahydrofuran / 0.33 h / 20 °C

3: 97 percent / diisobutylaluminium hydride / CH₂Cl₂ / 1 h / 0 °C

4: 93 percent / imidazole / tetrahydrofuran / 1.5 h / 20 °C

5: 98 percent / p-toluenesulfonate pyridinium salt / ethanol / 20 °C

6: 100 percent / DMSO; oxalyl chloride; triethylamine / CH₂Cl₂ / 3 h / 20 °C

7: 93 percent / n-butyl lithium / hexane; tetrahydrofuran / 0.75 h / -78 °C

8: 100 percent / lithium aluminium hydride / tetrahydrofuran / 0.33 h / 0 °C

9: 99 percent / triphenylphosphine; hexachloroacetone / tetrahydrofuran / 0.33 h / -40 °C

With 1H-imidazole; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; 1,1,1,3,3,3-hexachloro-propan-2-one; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; triphenylphosphine; In tetrahydrofuran; ethanol; hexane; dichloromethane; 2: Horner-Emmons reaction / 6: Swern oxidation / 7: Horner-Emmons reaction;
DOI:10.1139/v05-259

Reference yield:

: 853061-14-0
2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methoxy-benzaldehyde

: 853061-31-1
tert-Butyl-{(E)-3-[2-((E)-5-chloro-4-fluoro-pent-3-enyl)-4-methoxy-phenyl]-allyloxy}-diphenyl-silane

Guidance literature:: Multi-step reaction with 8 steps

1: 97 percent / sodium hydride / tetrahydrofuran / 0.33 h / 20 °C

2: 97 percent / diisobutylaluminium hydride / CH₂Cl₂ / 1 h / 0 °C

3: 93 percent / imidazole / tetrahydrofuran / 1.5 h / 20 °C

4: 98 percent / p-toluenesulfonate pyridinium salt / ethanol / 20 °C

5: 100 percent / DMSO; oxalyl chloride; triethylamine / CH₂Cl₂ / 3 h / 20 °C

6: 93 percent / n-butyl lithium / hexane; tetrahydrofuran / 0.75 h / -78 °C

7: 100 percent / lithium aluminium hydride / tetrahydrofuran / 0.33 h / 0 °C

8: 99 percent / triphenylphosphine; hexachloroacetone / tetrahydrofuran / 0.33 h / -40 °C

With 1H-imidazole; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; 1,1,1,3,3,3-hexachloro-propan-2-one; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; triphenylphosphine; In tetrahydrofuran; ethanol; hexane; dichloromethane; 1: Horner-Emmons reaction / 5: Swern oxidation / 6: Horner-Emmons reaction;
DOI:10.1139/v05-259