(6R,10S,14S,18R)-2,2,6,10,14,18,23,23-octamethyl-3,3,22,22-tetraphenyl-17-(triethylsilyloxy)-4,21-dioxa-3,22-disilatetracos-11-en-10-ol

Base Information

Chemical Name:(6R,10S,14S,18R)-2,2,6,10,14,18,23,23-octamethyl-3,3,22,22-tetraphenyl-17-(triethylsilyloxy)-4,21-dioxa-3,22-disilatetracos-11-en-10-ol
CAS No.:1255910-72-5
Molecular Formula:C₅₈H₉₀O₄Si₃
Molecular Weight:935.607
Hs Code.:

Synonyms:(6R,10S,14S,18R)-2,2,6,10,14,18,23,23-octamethyl-3,3,22,22-tetraphenyl-17-(triethylsilyloxy)-4,21-dioxa-3,22-disilatetracos-11-en-10-ol

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Chemical Property of (6R,10S,14S,18R)-2,2,6,10,14,18,23,23-octamethyl-3,3,22,22-tetraphenyl-17-(triethylsilyloxy)-4,21-dioxa-3,22-disilatetracos-11-en-10-ol

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Technology Process of (6R,10S,14S,18R)-2,2,6,10,14,18,23,23-octamethyl-3,3,22,22-tetraphenyl-17-(triethylsilyloxy)-4,21-dioxa-3,22-disilatetracos-11-en-10-ol

There total 1 articles about (6R,10S,14S,18R)-2,2,6,10,14,18,23,23-octamethyl-3,3,22,22-tetraphenyl-17-(triethylsilyloxy)-4,21-dioxa-3,22-disilatetracos-11-en-10-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 1255910-55-4
(3S,7R)-8-(tert-butyldiphenylsilyloxy)-3,7-dimethyloct-1-en-3-ol

: 1255910-53-2
(7R)-10,10-diethyl-2,2,7-trimethyl-8-((S)-3-methylhex-5-enyl)-3,3-diphenyl-4,9-dioxa-3,10-disiladodecane

: 1255910-72-5
(6R,10S,14S,18R)-2,2,6,10,14,18,23,23-octamethyl-3,3,22,22-tetraphenyl-17-(triethylsilyloxy)-4,21-dioxa-3,22-disilatetracos-11-en-10-ol

Guidance literature:: With Hoveyda-Grubbs catalyst second generation; In α,α,α-trifluorotoluene; at 85 ℃; for 2h; Inert atmosphere;
DOI:10.1021/ol102177j

Reference yield: 67.0%

: 1255910-72-5
(6R,10S,14S,18R)-2,2,6,10,14,18,23,23-octamethyl-3,3,22,22-tetraphenyl-17-(triethylsilyloxy)-4,21-dioxa-3,22-disilatetracos-11-en-10-ol

: 1255910-67-8
(7R,11R,15R,19R)-15-hydroxy-2,2,7,11,15,19,23,23-octamethyl-3,3,22,22-tetraphenyl-4,21-dioxa-3,22-disilatetracosan-8-one

Guidance literature:: (6R,10S,14S,18R)-2,2,6,10,14,18,23,23-octamethyl-3,3,22,22-tetraphenyl-17-(triethylsilyloxy)-4,21-dioxa-3,22-disilatetracos-11-en-10-ol; With palladium 10% on activated carbon; hydrogen; In methanol; at 20 ℃; for 12h;

In methanol; at 20 ℃; for 2h; Inert atmosphere;

With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/ol102177j