3,4-di-O-benzyl-1,2-O-(α-methoxybenzylidene)-6-O-(triisopropylsilyl)-β-D-mannopyranose

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Chemical Name:3,4-di-O-benzyl-1,2-O-(α-methoxybenzylidene)-6-O-(triisopropylsilyl)-β-D-mannopyranose
CAS No.:883878-96-4
Molecular Formula:C₃₇H₅₀O₇Si
Molecular Weight:634.885
Hs Code.:

Synonyms:3,4-di-O-benzyl-1,2-O-(α-methoxybenzylidene)-6-O-(triisopropylsilyl)-β-D-mannopyranose

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Chemical Property of 3,4-di-O-benzyl-1,2-O-(α-methoxybenzylidene)-6-O-(triisopropylsilyl)-β-D-mannopyranose

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Technology Process of 3,4-di-O-benzyl-1,2-O-(α-methoxybenzylidene)-6-O-(triisopropylsilyl)-β-D-mannopyranose

There total 3 articles about 3,4-di-O-benzyl-1,2-O-(α-methoxybenzylidene)-6-O-(triisopropylsilyl)-β-D-mannopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 915150-04-8
1,2-O-(α-methoxybenzylidene)-6-O-(triisopropylsilyl)-β-D-mannopyranose

: 100-39-0
benzyl bromide

: 883878-96-4
3,4-di-O-benzyl-1,2-O-(α-methoxybenzylidene)-6-O-(triisopropylsilyl)-β-D-mannopyranose

Guidance literature:: With 1H-imidazole; sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃;
DOI:10.1021/jo061233x

Reference yield:

: 14218-11-2,14218-30-5,61198-88-7,108438-33-1,108836-02-8,114682-36-9,127305-34-4,151377-77-4
2,3,4,6-Tetra-O-benzoyl-α-D-mannopyranosyl bromide

: 883878-96-4
3,4-di-O-benzyl-1,2-O-(α-methoxybenzylidene)-6-O-(triisopropylsilyl)-β-D-mannopyranose

Guidance literature:: Multi-step reaction with 4 steps

1: 2,6-lutidine / CH₂Cl₂ / 72 h / 20 °C

2: 2.40 g / NaOMe / methanol / 24 h / 24 °C

3: 66 percent / imidazole / dimethylformamide / 0 - 20 °C

4: 95 percent / imidazole; NaH / dimethylformamide / 0 - 20 °C

With 1H-imidazole; 2,6-dimethylpyridine; sodium methylate; sodium hydride; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo061233x

Reference yield:

: 98467-54-0
1,2-O-(α-methoxybenzylidene)-β-D-mannopyranose

: 883878-96-4
3,4-di-O-benzyl-1,2-O-(α-methoxybenzylidene)-6-O-(triisopropylsilyl)-β-D-mannopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: 66 percent / imidazole / dimethylformamide / 0 - 20 °C

2: 95 percent / imidazole; NaH / dimethylformamide / 0 - 20 °C

With 1H-imidazole; sodium hydride; In N,N-dimethyl-formamide;
DOI:10.1021/jo061233x