[Na][Ru(azide)₂{κ³(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh₃)]

Base Information

• Chemical Name: [Na][Ru(azide)₂{κ³(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh₃)]
• CAS No.: 1428867-61-1
• Molecular Formula: C₂₈H₂₄N₁₂O₃PRuS*Na
• Molecular Weight: 763.677
• Mol file: 1428867-61-1.mol

Synonyms:[Na][Ru(azide)₂{κ³(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh₃)]

Chemical Property of [Na][Ru(azide)₂{κ³(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh₃)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Na][Ru(azide)₂{κ³(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh₃)]

There total 1 articles about [Na][Ru(azide)₂{κ³(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh₃)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

sodium azide + [RuCl{κ3(N,N,N)-tris(pyrazol-1-yl)methanesulfonate}(PPh3)2] (1351467-91-8,1351468-05-7) → [Na][Ru(azide)2{κ3(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh3)] (1428867-61-1)

Guidance literature:

In methanol; dichloromethane; at 65 ℃; for 4h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ic302264t

Reference yield: 88.0%

[Na][Ru(azide)2{κ3(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh3)] (1428867-61-1) + benzonitrile (100-47-0) → [Ru(azide)(benzonitrile){κ3(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh3)] (1428867-68-8)

Guidance literature:

In toluene; for 5h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1021/ic302264t

Reference yield: 86.0%

[Na][Ru(azide)2{κ3(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh3)] (1428867-61-1) + acetonitrile (75-05-8,26809-02-9) → [Ru(azide)(acetonitrile){κ3(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh3)] (1428867-67-7)

Guidance literature:

for 144h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1021/ic302264t

upstream raw materials:

[RuCl{κ³(N,N,N)-tris(pyrazol-1-yl)methanesulfonate}(PPh₃)₂]

Downstream raw materials:

[Na][Ru{κ(N²)-N₃C₂(CO₂Me)₂}₂{κ³(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh₃)]

[Na][Ru{κ(N²)-N₃C₂(CO₂Et)₂}₂{κ³(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh₃)]

[Na][Ru{N₃C₂HCO₂Me}₂{κ³(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh₃)]

[Na][Ru(azide){N₃C₂HCO₂Me}{κ³(N,N,N)-tris(pyrazolyl)methanesulfonate}(PPh₃)]