Benzyl-((E)-buta-1,3-dienyl)-[(Z)-1-(tert-butyl-dimethyl-silanyloxy)-propenyl]-amine

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Chemical Name:Benzyl-((E)-buta-1,3-dienyl)-[(Z)-1-(tert-butyl-dimethyl-silanyloxy)-propenyl]-amine
CAS No.:182820-98-0
Molecular Formula:C₂₀H₃₁NOSi
Molecular Weight:329.558
Hs Code.:

Synonyms:Benzyl-((E)-buta-1,3-dienyl)-[(Z)-1-(tert-butyl-dimethyl-silanyloxy)-propenyl]-amine

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Chemical Property of Benzyl-((E)-buta-1,3-dienyl)-[(Z)-1-(tert-butyl-dimethyl-silanyloxy)-propenyl]-amine

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Technology Process of Benzyl-((E)-buta-1,3-dienyl)-[(Z)-1-(tert-butyl-dimethyl-silanyloxy)-propenyl]-amine

There total 4 articles about Benzyl-((E)-buta-1,3-dienyl)-[(Z)-1-(tert-butyl-dimethyl-silanyloxy)-propenyl]-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 152710-48-0
N-benzyl-N-[(E)-buta-1,3-dienyl]propanamide

: 182820-98-0
Benzyl-((E)-buta-1,3-dienyl)-[(Z)-1-(tert-butyl-dimethyl-silanyloxy)-propenyl]-amine

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide; In tetrahydrofuran; at -78 - 20 ℃; for 2h;
DOI:10.1016/0040-4020(96)00646-1

Reference yield:

: 183311-38-8
N-benzyl-N-but-2-enylideneamine

: 182820-98-0
Benzyl-((E)-buta-1,3-dienyl)-[(Z)-1-(tert-butyl-dimethyl-silanyloxy)-propenyl]-amine

Guidance literature:: Multi-step reaction with 2 steps

1.1: PhNEt₂

2.1: LDA; HMPA / tetrahydrofuran

2.2: tetrahydrofuran

With N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-diethylaniline; lithium diisopropyl amide; In tetrahydrofuran; 1.1: Acylation / 2.1: Metallation / 2.2: Etherification;
DOI:10.1002/(SICI)1521-3765(19991105)5:11<3162::AID-CHEM3162>3.0.CO;2-H

Reference yield:

: 100-46-9
benzylamine

: 182820-98-0
Benzyl-((E)-buta-1,3-dienyl)-[(Z)-1-(tert-butyl-dimethyl-silanyloxy)-propenyl]-amine

Guidance literature:: Multi-step reaction with 3 steps

1.1: molecular sieves 4 Angstroem / diethyl ether

2.1: PhNEt₂

3.1: LDA; HMPA / tetrahydrofuran

3.2: tetrahydrofuran

With N,N,N,N,N,N-hexamethylphosphoric triamide; 4 A molecular sieve; N,N-diethylaniline; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; 1.1: Condensation / 2.1: Acylation / 3.1: Metallation / 3.2: Etherification;
DOI:10.1002/(SICI)1521-3765(19991105)5:11<3162::AID-CHEM3162>3.0.CO;2-H