(4-Vinylphenyl)methanol

Base Information

• Chemical Name: (4-Vinylphenyl)methanol
• CAS No.: 1074-61-9
• Molecular Formula: C9H10O
• Molecular Weight: 134.178
• Hs Code.: 2906299090
• UNII: 6BHO7I62RA
• DSSTox Substance ID: DTXSID80370612
• Nikkaji Number: J611.577B
• Wikidata: Q27894796
• Metabolomics Workbench ID: 182947
• Mol file: 1074-61-9.mol

Synonyms:(4-Vinylphenyl)methanol;1074-61-9;4-Vinylbenzyl alcohol;(4-ethenylphenyl)methanol;4-VinylbenzylAlcohol;p-vinylbenzyl alcohol;4-Vinylbenzenemethanol;4-Ethenylbenzenemethanol;p-(Hydroxymethyl)styrene;6BHO7I62RA;(4-Vinyl-phenyl)-methanol;p-viny lbenzyl alcohol;UNII-6BHO7I62RA;SCHEMBL164874;SCHEMBL13341635;DTXSID80370612;CLECMSNCZUMKLM-UHFFFAOYSA-N;MFCD00016872;AKOS006281036;DS-4972;CS-0130741;FT-0602037;A21086;F14590;Q27894796

Chemical Property of (4-Vinylphenyl)methanol

Chemical Property:

• Vapor Pressure: 0.0139mmHg at 25°C
• Refractive Index: 1.59
• Boiling Point: 247.072 °C at 760 mmHg
• PKA: 14.38±0.10(Predicted)
• Flash Point: 115.435 °C
• PSA: 20.23000
• Density: 1.039 g/cm³
• LogP: 1.82190
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility.: Acetonitrile (Slightly), Chloroform (Slightly)
• XLogP3: 2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 134.073164938
• Heavy Atom Count: 10
• Complexity: 101

Purity/Quality:

95% ^*data from raw suppliers

(4-VINYL-PHENYL)-METHANOL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC1=CC=C(C=C1)CO
• General Description: (4-Vinylphenyl)methanol (also known as 4-vinylbenzyl alcohol) is a monomer used in polymerization reactions, such as palladium-catalyzed hydroesterification with CO to form polyesters, though its reactivity can lead to side reactions that limit polymer chain growth. It is also employed in the synthesis of functionalized polymer supports, such as polystyrene-grafted polytetrahydrofuran resins, due to its hydroxyl group, which facilitates modifications for solid-phase organic synthesis. Additionally, it serves as a component in high-refractive-index nanocomposites when polymerized with surface-modified TiO2 nanoparticles, enhancing optical and mechanical properties. Its versatility in polymerization and functional group reactivity makes it useful in materials science and organic synthesis.

Technology Process of (4-Vinylphenyl)methanol

There total 20 articles about (4-Vinylphenyl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-acetoxymethylstyrene (1592-12-7) → (4-vinyl-phenyl)-methanol (1074-61-9)

Guidance literature:

With sodium hydroxide; In ethanol; water; for 4h; Reflux;

DOI:10.1021/jacs.0c03184

Reference yield: 98.0%

4-Vinylbenzyl chloride (1592-20-7,29296-32-0) → (4-vinyl-phenyl)-methanol (1074-61-9)

Guidance literature:

With sodium hydroxide; tetrabutylammomium bromide; water; at 125 ℃; for 0.333333h;

DOI:10.1002/adsc.200700344

Reference yield: 95.0%

4-vinyl-benzaldehyde (1791-26-0) → (4-vinyl-phenyl)-methanol (1074-61-9)

Guidance literature:

With C₄₆H₄₉CoN₃P₄⁽²⁺⁾*2BF₄^(1-); hydrogen; potassium hydroxide; In ethanol; acetonitrile; at 60 ℃; for 24h; under 22801.5 Torr; chemoselective reaction; Autoclave; Glovebox;

DOI:10.1021/jacs.9b11070

upstream raw materials:

4-acetoxymethylstyrene

1-(2-chloroethyl)-4-(chloromethyl)benzene

1,1-dibromo-2-(4-methoxycarbonylphenyl)ethene

2,4,6,8-tetramethyl-2,4,6,8-tetravinyl-cyclotetrasiloxane

Downstream raw materials:

4-vinyl-benzaldehyde

{4-[1-(2,2,6,6-tetramethylpiperidin-1-yloxy)ethyl]phenyl}methanol

4-vinylbenzyl acetoacetate

triisopropyl-(4-vinyl-benzyloxy)-silane