1592-12-7

Basic information

• Product Name: 4-VINYLBENZYL ACETATE
• Synonyms: 4-VINYLBENZYL ACETATE;4-Vinylbenzyl acetate, stabilized, 95%;4-VINYLBENZYL ACETATE STABILIZED 95%;4-Vinylbenzyl acetate, 95%, stabilized;4-Vinylbenzyl acetate, stabilized, 95% 5GR
• CAS NO: 1592-12-7
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.21
• Mol File: 1592-12-7.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 125°C/12mmHg
• Flash Point: 110.7°C
• Appearance: White/Crystals or Crystalline Powder
• Density: 1.047g/cm³
• Vapor Pressure: 0.0194mmHg at 25°C
• Refractive Index: 1.535-1.538
• Storage Temp.: Refrigerator (+4°C)
• CAS DataBase Reference: 4-VINYLBENZYL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-VINYLBENZYL ACETATE(1592-12-7)
• EPA Substance Registry System: 4-VINYLBENZYL ACETATE(1592-12-7)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 1592-12-7(Hazardous Substances Data)

Usage

Chemical Properties

clear slightly yellow liquid

InChI:InChI=1/C11H12O2/c1-3-10-4-6-11(7-5-10)8-13-9(2)12/h3-7H,1,8H2,2H3

Upstream product

• 54549-74-5 4-(acetoxymethyl)benzaldehyde 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 1592-20-7 4-Vinylbenzyl chloride 
• 127-09-3 sodium acetate 
• 127-08-2 potassium acetate 
• 256449-39-5 4-acetoxymethyl-(1-(R,S)-acetoxyethyl)benzene 

Downstream Products

• 13368-25-7 1-(bromomethyl)-4-vinylbenzene 
• 1380650-22-5 C₂₉H₂₂O₂ 
• 1323999-45-6 C₃₀H₂₈N₂O₂ 
• 149636-62-4 O-(tert-butyl)dimethylsilyl(4-vinylphenyl)methanol 
• 1081852-38-1 (E)-4-styrylbenzyl acetate 
• 943767-46-2 4-(3,3,4,4,4-pentafluorobutyl)benzenemethanol acetate 

Relevant articles and documents

Visible light-promoted dihydroxylation of styrenes with water and dioxygen

An efficient visible light promoted metal-free dihydroxylation of styrenes with water and dioxygen has been developed for the construction of vicinal alcohols. The protocol was operationally simple with a broad substrate scope. The mechanistic studies demonstrated that one of the hydroxyl groups came from water and the other one came from molecular oxygen. Additionally, the β-alkyoxy alcohols could also be obtained using a similar strategy.

Synthesis and characterization of cross-linkable ruthenium dye with ion coordinating property for dye-sensitized solar cells

Crosslinkable ruthenium complex dye, Ru(2,2′-bipyridine-4,4′- bicarboxylic acid)(4,4′-bis((4-vinyl benzyloxy)methyl)-2,2′- bipyridine)(NCS)2 (denoted as Ru-S dye), was synthesized and characterized using 1H-NMR, 13C-NMR, Fourier transform infrared (FTIR) and UV/vis spectroscopies.The power conversion efficiency of dye-sentitized solar cell (DSSC) using Ru-S and liquid electrolyte containing lithium iodide (LiI) reached 7.53% under standard global AM 1.5 full sunlight, which is partly attributed to Li+ being coordinated by Ru-S as verified by ATR-FTIR spectroscopy. As Ru-S was further crosslinked with glycerol propoxylate triacrylate (GPTA), not only 89% of dye retained on TiO2 mesoporous surface after rinsed by 0.1 N NaOH aqueous solution, the power efficiency was also increased to 7.88%. As poly(methyl acrylate) was used to gel the electrolyte system, the power efficiency of DSSC with Ru-S dye was 6.96% but increased to 7.57% after crosslinking with GPTA. Notably, both DSSCs showed a good long-term stability after one month storage.

Ruthenium-catalyzed, one-pot alcohol oxidation-wittig reaction producing αβ unsaturated esters

By a one-pot process, αβ-unsaturated esters were synthesized in high yield through the Ru-catalyzed oxidation of primary alcohols and the coupling of the resulting aldehydes and stabilized Wittig reagents. The ruthenium catalyst is composed of ruthenium nanoparticles embedded in aluminum oxyhydroxide and can be recovered simply by filtration or decantation. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009.