ethyl 4-methyl-2-oxo-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate

Base Information

Chemical Name:ethyl 4-methyl-2-oxo-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate
CAS No.:1394291-05-4
Molecular Formula:C₁₄H₁₈O₄
Molecular Weight:250.295
Hs Code.:

Synonyms:ethyl 4-methyl-2-oxo-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate

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Chemical Property of ethyl 4-methyl-2-oxo-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate

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Technology Process of ethyl 4-methyl-2-oxo-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate

There total 1 articles about ethyl 4-methyl-2-oxo-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 40308-66-5
3-chloromethoxy-propyne

: 14619-42-2
ethyl 4-methyl-2-oxocyclohex-3-ene-1-carboxylate

: 1394291-05-4
ethyl 4-methyl-2-oxo-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride; In tetrahydrofuran; mineral oil; at -10 ℃; for 3h;
DOI:10.1039/c2ob26107c DOI:10.1039/c2ob26107c

Reference yield: 82.0%

: 1394291-05-4
ethyl 4-methyl-2-oxo-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate

: ethyl 2-hydroxy-4-methyl-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate

Guidance literature:: ethyl 4-methyl-2-oxo-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate; With cerium(III) chloride heptahydrate; In methanol; at -10 ℃; for 0.0833333h;

With sodium tetrahydroborate; In methanol; at -10 ℃; for 0.25h; stereoselective reaction;
DOI:10.1039/c2ob26107c DOI:10.1039/c2ob26107c

Reference yield:

: 1394291-05-4
ethyl 4-methyl-2-oxo-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate

: C₁₈H₃₂O₃Si

Guidance literature:: Multi-step reaction with 3 steps

1.1: cerium(III) chloride heptahydrate / methanol / 0.08 h / -10 °C

1.2: 0.25 h / -10 °C

2.1: 1H-imidazole / dichloromethane / 8 h / 0 °C

3.1: diisobutylaluminium hydride / dichloromethane; toluene / 1 h / 0 °C

With 1H-imidazole; cerium(III) chloride heptahydrate; diisobutylaluminium hydride; In methanol; dichloromethane; toluene; 1.1: |Luche Cerium Reduction / 1.2: |Luche Cerium Reduction;
DOI:10.1039/c2ob26107c DOI:10.1039/c2ob26107c