14619-42-2

Basic information

• Product Name: 3-Cyclohexene-1-carboxylic acid, 4-methyl-2-oxo-, ethyl ester
• CAS NO: 14619-42-2
• Molecular Formula: C10H14O3
• Molecular Weight: 182.219
• Mol File: 14619-42-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 3-Cyclohexene-1-carboxylic acid, 4-methyl-2-oxo-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexene-1-carboxylic acid, 4-methyl-2-oxo-, ethyl ester(14619-42-2)
• EPA Substance Registry System: 3-Cyclohexene-1-carboxylic acid, 4-methyl-2-oxo-, ethyl ester(14619-42-2)

Safety Data

• Hazardous Substances Data: 14619-42-2(Hazardous Substances Data)

Upstream product

• 26209-40-5 2-acetyl-5-chloro-hex-4-enoic acid ethyl ester 
• 35490-05-2 2-acetyl-5-oxohexanoic acid ethyl ester 
• 1193-18-6 3-methylcyclohexen-2-one 
• 1609-47-8 diethyl dicarbonate 
• 105-58-8 Diethyl carbonate 
• 141-97-9 ethyl acetoacetate 
• 78-94-4 methyl vinyl ketone 
• 623-49-4 ethyl cyanoformate 

Downstream Products

• 99-94-5 p-Toluic acid 
• 1297286-18-0 C₁₇H₃₀O₄Si 
• 60770-00-5 ethyl 4-methylsalicylate 
• 1394291-05-4 ethyl 4-methyl-2-oxo-1-((prop-2-yn-1-yloxy)methyl)cyclohex-3-enecarboxylate 

Relevant articles and documents

Convincing Catalytic Performance of Oxo-Tethered Ruthenium Complexes for Asymmetric Transfer Hydrogenation of Cyclic α-Halogenated Ketones through Dynamic Kinetic Resolution

A highly efficient dynamic kinetic resolution of cyclic halohydrins was achieved by the asymmetric transfer hydrogenation of racemic α-haloketones. Bifunctional oxo-tethered Ru(II) catalysts could promote the reduction without deterioration of halogens. By structural tuning of the catalyst, chiral alcohols having halogen, ester, carboxamide, and sulfone functions were obtained variably with excellent diastereo- and enantioselectivities (up to >99:1 d.r. and >99.9 ee), which provided a concise synthetic approach to a dopamine D3 receptor ligand, (+)-PHNO.

Design, synthesis, structure, and dehydrogenation reactivity of a water soluble o-iodoxybenzoic acid derivative bearing a trimethylammonium group

5-Trimethylammonio-1, 3-dioxo-1, 3-dihydro-1λ5-benzo[d][1, 2]iodoxol-1-ol anion (AIBX 1a), an o-iodoxybenzoic acid (IBX) derivative having the trimethylammonium moiety on its phenyl ring, possesses very good solubility in water and distinct oxidative properties from IBX, which is demonstrated in the oxidation of various β-keto esters to the corresponding dehydrogenated products using water as cosolvent. The regeneration of AIBX 1a can be easily realized from the reaction mixture due to its good water solubility.2011 American Chemical Society.

Diethyl Dicarbonate: A Convenient Reagent for the Preparation of β-Ketoesters

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