(C₅H₅)Re(NO)(P(C₆H₅)3)O₃SC₆H₄CH₃

Base Information

Chemical Name:(C₅H₅)Re(NO)(P(C₆H₅)3)O₃SC₆H₄CH₃
CAS No.:92695-37-9
Molecular Formula:C₃₀H₂₇NO₄PReS
Molecular Weight:714.795
Hs Code.:

(C<sub>5</sub>H<sub>5</sub>)Re(NO)(P(C<sub>6</sub>H<sub>5</sub>)3)O<sub>3</sub>SC<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>

Synonyms:(C₅H₅)Re(NO)(P(C₆H₅)3)O₃SC₆H₄CH₃

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Chemical Property of (C₅H₅)Re(NO)(P(C₆H₅)3)O₃SC₆H₄CH₃

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Technology Process of (C₅H₅)Re(NO)(P(C₆H₅)3)O₃SC₆H₄CH₃

There total 1 articles about (C₅H₅)Re(NO)(P(C₆H₅)3)O₃SC₆H₄CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: (η5-C5H5)(Me)(NO)(PPh3)rhenium(II)

: 6192-52-5
p-toluenesulfonic acid monohydrate

: 92695-37-9
(C₅H₅)Re(NO)(P(C₆H₅)3)O₃SC₆H₄CH₃

Guidance literature:: In dichloromethane; soln. of Re-complex in CH2Cl2 and 1.1 equiv of p-CH3C6H4SO3H*H2O were stirred for 1 h at room temp.; solvent removed under vac., extd. with benzene, filtered, ether added slowly to filtrate by vapor diffusion, filtered; elem. anal.;

Reference yield: 96.0%

: 92695-37-9
(C₅H₅)Re(NO)(P(C₆H₅)3)O₃SC₆H₄CH₃

: 1017-60-3
di-p-tolylphosphine

: 113158-32-0
(C₅H₅)Re(NO)(P(C₆H₅)3)P(C₆H₄CH₃)2H⁽¹⁺⁾*O₃SC₆H₄CH₃^(1-)={(C₅H₅)Re(NO)(P(C₆H₅)3)P(C₆H₄CH₃)2H}{O₃SC₆H₄CH₃}

Guidance literature:: In dichloromethane; (C5H5)Re(NO)PpO3SC6H4CH3 and P(C6H4CH3)2H stirred in CH2Cl2 for 2 d; soln. concd. in vacuo; formed oil after addn. of ether washed with ether and redissolved in benzene; after addn. of ether ppt. formed, filtered and dried in vacuo at 56 ° C; elem. anal.;
DOI:10.1021/ja00216a015

Reference yield: 94.0%

: 92695-37-9
(C₅H₅)Re(NO)(P(C₆H₅)3)O₃SC₆H₄CH₃

: 829-85-6
diphenylphosphane

: 96213-74-0
(C₅H₅)Re(NO)(P(C₆H₅)3)P(C₆H₅)2H⁽¹⁺⁾*O₃SC₆H₄CH₃^(1-)={(C₅H₅)Re(NO)(P(C₆H₅)3)P(C₆H₅)2H}{O₃SC₆H₄CH₃}

Guidance literature:: In dichloromethane; (C5H5)Re(NO)PpO3SC6H4CH3 and PPh2H stirred in CH2Cl2 for 2 d; soln. concd. in vacuo and added to ether; formed ppt. filtered, washed with ether, air-dried, recrystallized from CHCl3/ether and dried in vacuo; elem. anal.;
DOI:10.1021/ja00216a015