<3(2R,3S,4R,5S,6S),4R,5S>-3-<1-oxo-2-<(4-methoxyphenyl)methoxy>-3,4,6-trihydroxy-4,6-O--7-methyleneoctyl>-4-methyl-5-phenyl-2-oxazolidinone

Base Information

Chemical Name:<3(2R,3S,4R,5S,6S),4R,5S>-3-<1-oxo-2-<(4-methoxyphenyl)methoxy>-3,4,6-trihydroxy-4,6-O--7-methyleneoctyl>-4-methyl-5-phenyl-2-oxazolidinone
CAS No.:129986-23-8
Molecular Formula:C₃₆H₅₁NO₈Si
Molecular Weight:653.888
Hs Code.:

<3(2R,3S,4R,5S,6S),4R,5S>-3-<1-oxo-2-<(4-methoxyphenyl)methoxy>-3,4,6-trihydroxy-4,6-O-<bis(1,1-dimethylethyl)silylene>-7-methyleneoctyl>-4-methyl-5-phenyl-2-oxazolidinone

Synonyms:<3(2R,3S,4R,5S,6S),4R,5S>-3-<1-oxo-2-<(4-methoxyphenyl)methoxy>-3,4,6-trihydroxy-4,6-O--7-methyleneoctyl>-4-methyl-5-phenyl-2-oxazolidinone

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Chemical Property of <3(2R,3S,4R,5S,6S),4R,5S>-3-<1-oxo-2-<(4-methoxyphenyl)methoxy>-3,4,6-trihydroxy-4,6-O--7-methyleneoctyl>-4-methyl-5-phenyl-2-oxazolidinone

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Technology Process of <3(2R,3S,4R,5S,6S),4R,5S>-3-<1-oxo-2-<(4-methoxyphenyl)methoxy>-3,4,6-trihydroxy-4,6-O--7-methyleneoctyl>-4-methyl-5-phenyl-2-oxazolidinone

There total 10 articles about <3(2R,3S,4R,5S,6S),4R,5S>-3-<1-oxo-2-<(4-methoxyphenyl)methoxy>-3,4,6-trihydroxy-4,6-O--7-methyleneoctyl>-4-methyl-5-phenyl-2-oxazolidinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 88920-24-5
p-methoxybenzyloxy acetic acid

: 129986-23-8
<3(2R,3S,4R,5S,6S),4R,5S>-3-<1-oxo-2-<(4-methoxyphenyl)methoxy>-3,4,6-trihydroxy-4,6-O--7-methyleneoctyl>-4-methyl-5-phenyl-2-oxazolidinone

Guidance literature:: Multi-step reaction with 3 steps

1: Et₃N / diethyl ether / 1.58 h / -78 - 0 °C

2: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 10 min, 2.) a) ether, -70 deg C, 45 min, b) 0 deg C, 6 h

With n-butyllithium; triethylamine; In diethyl ether;
DOI:10.1021/ja00175a038

Reference yield:

: 129986-21-6
<2R,3S,4S>-2,4-O--3-methyl-5-methylene-1,2,4-hexanetriol

: 129986-23-8
<3(2R,3S,4R,5S,6S),4R,5S>-3-<1-oxo-2-<(4-methoxyphenyl)methoxy>-3,4,6-trihydroxy-4,6-O--7-methyleneoctyl>-4-methyl-5-phenyl-2-oxazolidinone

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / oxalyl chloride, DMSO / CH₂Cl₂ / 0.25 h / -78 °C

With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane;
DOI:10.1021/ja00175a038

Reference yield:

: 129986-20-5
<2R,3R>-3-hydroxy-N-methoxy-N,2-dimethyl-4-(phenylmethoxy)butanamide

: 129986-23-8
<3(2R,3S,4R,5S,6S),4R,5S>-3-<1-oxo-2-<(4-methoxyphenyl)methoxy>-3,4,6-trihydroxy-4,6-O--7-methyleneoctyl>-4-methyl-5-phenyl-2-oxazolidinone

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) lithium / 1.) Et₂O, from 0 deg C to RT, 14.5 h, 2.) THF, -78 deg C, 40 min

2: 99 percent / methoxydiethylborane, NaBH₄ / tetrahydrofuran; methanol / 4 h / -70 °C

3: 97 percent / 2,6-lutidine / CH₂Cl₂ / 9 h / 65 °C

4: 80 percent / Ca/NH₃ / tetrahydrofuran / 0.4 h / -63 - -45 °C

5: 97 percent / oxalyl chloride, DMSO / CH₂Cl₂ / 0.25 h / -78 °C

With 2,6-dimethylpyridine; sodium tetrahydroborate; oxalyl dichloride; diethyl methoxy borane; ammonia; lithium; calcium; dimethyl sulfoxide; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ja00175a038