129986-20-5Relevant articles and documents
Enantioselective synthesis of δ-/γ-alkoxy-β-hydroxy- α-alkyl-substituted Weinreb amides via DKR-ATH: Application to the synthesis of advanced intermediate of (-)-brevisamide
Kumaraswamy, Gullapalli,Narayana Murthy, Akula,Narayanarao, Vykunthapu,Vemulapalli, Sahithya Phani Babu,Bharatam, Jagadeesh
, p. 6751 - 6765 (2013/10/01)
A method of preparing stereodefined δ-/γ-alkoxy-β-hydroxy- α-alkyl-substituted Weinreb amides containing two successive hydroxyl-alkyl stereocenters has been developed. Further, this strategy coupled with organo-catalyzed asymmetric epoxidation culminates in the synthesis of a critical intermediate of (-)-brevisamide and its diastereomers.
Stereocontrolled total synthesis of (-)-ebelactone A.
Mandal, Amit K
, p. 2043 - 2045 (2007/10/03)
[structure: see text] The highly stereocontrolled hydroboration of an alkene, a subsequent Suzuki-Miyaura cross-coupling reaction, a silylcupration on a nonterminal acetylene, and an iododesilylation were the key steps in a convergent total synthesis of (