diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate

Base Information

Chemical Name:diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate
CAS No.:733746-88-8
Molecular Formula:C₂₆H₂₈FeO₃P₂
Molecular Weight:506.301
Hs Code.:

Synonyms:diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate

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Chemical Property of diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate

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Technology Process of diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate

There total 1 articles about diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 185223-97-6
1′-(diphenylphosphino)-1-bromoferrocene

: 814-49-3
diethyl chlorophosphate

: 733746-88-8
diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate

Guidance literature:: With butyllithium; In tetrahydrofuran; hexane; byproducts: LiCl; under Ar, hexane soln. of BuLi (6 mmol) added with stirring to Fe compd.(5 mmol) in THF at -80°C, stirred for 30 min, treated with ligan d (6 mmol), stirred for 15 min at -80°C; stirred for 3 h at room temp., evapd. (vac.), chromd. (alumina, CHCl3/Et2O=2:3), evapd., crystd. on storage at 4°C, elem. anal.;
DOI:10.1002/ejic.200500725

Reference yield: 93.0%

: 733746-88-8
diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate

: mercury dibromide

: [Hg(μ-Br)Br(diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate]-κ2O1,P2)]2

Guidance literature:: With CH₃I; In acetone; under Ar, solid Fe compd. (0.11 mmol) and Zn compd. (0.10 mmol) in benzene, stirred for 1 d, methyl iodide (5 mmol) added, stirred for 1 h at room temp.; stored at 0°C overnight; evapd., dissolved (acetone), crystd. (Et2O), filtered off, washed (Et2O), dried (vac.), elem. anal.;
DOI:10.1002/ejic.200500725

Reference yield: 87.0%

: 733746-88-8
diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate

: mercury dibromide

: 916899-19-9,916899-18-8
[Hg(μ-Br)Br(diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate]-κP2)]2

Guidance literature:: In acetone; under Ar, solid Fe compd. (0.11 mmol) and Zn compd. (0.10 mmol) in acetone, stirred for 30 min at room temp.; crystd. on storage at -18°C for 1 d; filtered off, washed (Et2O),dried (vac.), elem. anal.;
DOI:10.1002/ejic.200500725