diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate

Base Information

• Chemical Name: diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate
• CAS No.: 733746-88-8
• Molecular Formula: C₂₆H₂₈FeO₃P₂
• Molecular Weight: 506.301
• Mol file: 733746-88-8.mol

Synonyms:diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate

Chemical Property of diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate

There total 1 articles about diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1′-(diphenylphosphino)-1-bromoferrocene (185223-97-6) + diethyl chlorophosphate (814-49-3) → diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate (733746-88-8)

Guidance literature:

With butyllithium; In tetrahydrofuran; hexane; byproducts: LiCl; under Ar, hexane soln. of BuLi (6 mmol) added with stirring to Fe compd.(5 mmol) in THF at -80°C, stirred for 30 min, treated with ligan d (6 mmol), stirred for 15 min at -80°C; stirred for 3 h at room temp., evapd. (vac.), chromd. (alumina, CHCl3/Et2O=2:3), evapd., crystd. on storage at 4°C, elem. anal.;

DOI:10.1002/ejic.200500725

Reference yield: 93.0%

diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate (733746-88-8) + mercury dibromide → [Hg(μ-Br)Br(diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate]-κ2O1,P2)]2

Guidance literature:

With CH₃I; In acetone; under Ar, solid Fe compd. (0.11 mmol) and Zn compd. (0.10 mmol) in benzene, stirred for 1 d, methyl iodide (5 mmol) added, stirred for 1 h at room temp.; stored at 0°C overnight; evapd., dissolved (acetone), crystd. (Et2O), filtered off, washed (Et2O), dried (vac.), elem. anal.;

DOI:10.1002/ejic.200500725

Reference yield: 87.0%

diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate (733746-88-8) + mercury dibromide → [Hg(μ-Br)Br(diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate]-κP2)]2 (916899-19-9,916899-18-8)

Guidance literature:

In acetone; under Ar, solid Fe compd. (0.11 mmol) and Zn compd. (0.10 mmol) in acetone, stirred for 30 min at room temp.; crystd. on storage at -18°C for 1 d; filtered off, washed (Et2O),dried (vac.), elem. anal.;

DOI:10.1002/ejic.200500725

upstream raw materials:

1′-(diphenylphosphino)-1-bromoferrocene

diethyl chlorophosphate

Downstream raw materials:

1-diphenylphosphino-1'-phosphinoferrocene

trans-[Pd(μ-Cl)Cl(diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate]-κP2)]2

[ZnBr2(diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate]-κ2O1,P2)]

[Hg(μ-Br)Br(diethyl [1'-(diphenylphosphanyl)ferrocenyl]phosphonate]-κP2)]2