1′-(diphenylphosphino)-1-bromoferrocene

Base Information

Chemical Name:1′-(diphenylphosphino)-1-bromoferrocene
CAS No.:185223-97-6
Molecular Formula:C₂₂H₁₈BrFeP
Molecular Weight:449.11
Hs Code.:

Synonyms:1′-(diphenylphosphino)-1-bromoferrocene

Suppliers and Price of 1′-(diphenylphosphino)-1-bromoferrocene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 1′-(diphenylphosphino)-1-bromoferrocene

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 1′-(diphenylphosphino)-1-bromoferrocene

There total 2 articles about 1′-(diphenylphosphino)-1-bromoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1293-65-8
1,1'-dibromoferrocene

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 185223-97-6
1′-(diphenylphosphino)-1-bromoferrocene

Guidance literature:: 1,1'-dibromoferrocene; With potassium tert-butylate; tert.-butyl lithium; Inert atmosphere; Schlenk technique;

chloro-diphenylphosphine; Inert atmosphere; Schlenk technique;
DOI:10.1039/c6cc02809h

Reference yield:

: 109-72-8,29786-93-4
n-butyllithium

: 1293-65-8
1,1'-dibromoferrocene

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 185223-97-6
1′-(diphenylphosphino)-1-bromoferrocene

: 1094756-39-4
1-bromo-2-(diphenylphosphino)ferrocene

Guidance literature:: With 2,2,6,6-tetramethyl-piperidine; In tetrahydrofuran; Fe-compound lithiated in THF at -70°C with n-BuLi; 2,2,6,6-tetramethylpiperidine added; allowed to warm slowly; cooled to -50°C; quenched with organic ligand; mixt. of two isomeric products formed: 1,1'-compound:1,2-compound=60:40 molar ratio;
DOI:10.1016/j.inoche.2007.09.020