8-(4-methoxy-2,6-dimethylphenyl)-2-(6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl)-1,10-phenanthroline

Base Information

Chemical Name:8-(4-methoxy-2,6-dimethylphenyl)-2-(6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl)-1,10-phenanthroline
CAS No.:1056700-91-4
Molecular Formula:C₃₅H₃₁N₃O₂
Molecular Weight:525.65
Hs Code.:

Synonyms:8-(4-methoxy-2,6-dimethylphenyl)-2-(6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl)-1,10-phenanthroline

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Chemical Property of 8-(4-methoxy-2,6-dimethylphenyl)-2-(6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl)-1,10-phenanthroline

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Technology Process of 8-(4-methoxy-2,6-dimethylphenyl)-2-(6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl)-1,10-phenanthroline

There total 1 articles about 8-(4-methoxy-2,6-dimethylphenyl)-2-(6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl)-1,10-phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 1056700-74-3
8-bromo-2-[6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl]-1,10-phenanthroline

: 361543-99-9
4-methoxy-2,6-dimethylphenylboronic acid

: 1056700-91-4
8-(4-methoxy-2,6-dimethylphenyl)-2-(6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl)-1,10-phenanthroline

Guidance literature:: 8-bromo-2-[6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl]-1,10-phenanthroline; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.0833333h; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

4-methoxy-2,6-dimethylphenylboronic acid; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; hexane; at 20 ℃; Inert atmosphere; Reflux;
DOI:10.1039/b804106g

Reference yield: 20.0%

: 17084-13-8
potassium hexafluorophosphate

: dichlorotetrakis(dimethylsulfoxide)ruthenium(II)

: 1056700-91-4
8-(4-methoxy-2,6-dimethylphenyl)-2-(6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl)-1,10-phenanthroline

: [Ru(8-(4-methoxy-2,6-dimethylphenyl)-2-(6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl)-1,10-phenanthroline)2](PF₆)2

: 1056701-04-2
[RuCl(8-(4-methoxy-2,6-dimethylphenyl)-2-(6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl)-1,10-phenanthroline)2]PF₆

Guidance literature:: In ethylene glycol; (Ar); heating ethylene glycol soln. of phenanthroline deriv. and ruthenium compd. at 125°C for 4 h; cooling to room temp., addn. of satd. aq. soln. of KPF6, filtration, washing with water and diethyl ether, dissolving in CH2Cl2, drying over MgSO4, filtration, evapn., chromy. (silica gel, CH3CN-H2O-satd. KPF6 (100:0:0, 97:3:0.3, 95:5:0.5), ESI-MS;
DOI:10.1039/b804106g