3,6-Dibromo-9-(2-ethylhexyl)-9H-carbazole

Base Information

• Chemical Name: 3,6-Dibromo-9-(2-ethylhexyl)-9H-carbazole
• CAS No.: 173063-52-0
• Molecular Formula: C20H23 Br2 N
• Molecular Weight: 437.217
• Hs Code.: 2933990090
• European Community (EC) Number: 835-320-7
• DSSTox Substance ID: DTXSID40587840
• Nikkaji Number: J709.378K
• Mol file: 173063-52-0.mol

Synonyms:3,6-Dibromo-9-(2-ethylhexyl)-9H-carbazole;173063-52-0;3,6-Dibromo-9-(2-ethylhexyl)carbazole;SCHEMBL923358;DTXSID40587840;YGA06352;MFCD18252907;AKOS016011706;3,6-dibromo-n-(2-ethylhexyl)carbazole;3,6-dibromo-9-(2-ethylhexyl)-carbazole;AS-65013;9-(2'-Ethylhexyl)-3,6-dibromo carbazole;DB-339047;CS-0186748;D4830;A881811;Q-101189

Chemical Property of 3,6-Dibromo-9-(2-ethylhexyl)-9H-carbazole

Chemical Property:

• PSA: 4.93000
• LogP: 7.53590
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 7.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 437.01768
• Heavy Atom Count: 23
• Complexity: 349

Purity/Quality:

97% ^*data from raw suppliers

3,6-Dibromo-9-(2-ethylhexyl)carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC(CC)CN1C2=C(C=C(C=C2)Br)C3=C1C=CC(=C3)Br

Technology Process of 3,6-Dibromo-9-(2-ethylhexyl)-9H-carbazole

There total 9 articles about 3,6-Dibromo-9-(2-ethylhexyl)-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.2%

3-bromomethylheptane (18908-66-2) + 3,6-dibromo-9H-carbazole (6825-20-3) → 3,6-dibromo-9-(2-ethyl-hexyl)-9H-carbazole (173063-52-0)

Guidance literature:

3,6-dibromo-9H-carbazole; With potassium tert-butylate; In tetrahydrofuran; at 20 ℃; Inert atmosphere; Schlenk technique;

3-bromomethylheptane; In tetrahydrofuran; Reflux; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.inorgchem.6b00523

Reference yield: 93.0%

N-(2-ethylhexyl)carbazole (187148-77-2) → 3,6-dibromo-9-(2-ethyl-hexyl)-9H-carbazole (173063-52-0)

Guidance literature:

With N-Bromosuccinimide; In N,N-dimethyl-formamide; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/acs.inorgchem.0c02366

Reference yield:

N-(2-ethylhexyl)carbazole (187148-77-2) → 3-bromo-9-(2-ethylhexyl)-9H-carbazole (628336-85-6) + 3,6-dibromo-9-(2-ethyl-hexyl)-9H-carbazole (173063-52-0)

Guidance literature:

With N-Bromosuccinimide; In tetrahydrofuran; at 0 ℃; for 1h;

DOI:10.1039/c4tc02931c

upstream raw materials:

3-bromomethylheptane

3,6-dibromo-9H-carbazole

9H-carbazole

N-(2-ethylhexyl)carbazole

Downstream raw materials:

9-(2-ethylhexyl)-3,6-bis(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-9H-carbazole

[HN(C₆H₃CCPt(C₆H₅)(P(C₂H₅)3)2)2]