6,6′-((1E,1′E)-(naphthalene-1,5-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol)

Base Information

• Chemical Name: 6,6′-((1E,1′E)-(naphthalene-1,5-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol)
• CAS No.: 1280575-75-8
• Molecular Formula: C₂₆H₂₂N₂O₄
• Molecular Weight: 426.472
• Mol file: 1280575-75-8.mol

Synonyms:6,6′-((1E,1′E)-(naphthalene-1,5-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol)

Chemical Property of 6,6′-((1E,1′E)-(naphthalene-1,5-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6,6′-((1E,1′E)-(naphthalene-1,5-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol)

There total 2 articles about 6,6′-((1E,1′E)-(naphthalene-1,5-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

3-methoxy-2-hydroxybenzaldehyde (148-53-8) + 1,5-naphthalenediamine (2243-62-1) → 6,6′-((1E,1′E)-(naphthalene-1,5-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol) (1280575-75-8)

Guidance literature:

In methanol; at 80 ℃; for 6h;

DOI:10.1016/j.bioorg.2021.105507

Reference yield:

N,N'-bis(2-hydroxy-3-methoxybenzyliden)-1,5-diaminonaphthalene (183659-47-4) → 6,6′-((1E,1′E)-(naphthalene-1,5-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol) (1280575-75-8)

Guidance literature:

UV-irradiation;

DOI:10.1039/c6ce00266h

Reference yield: 70.0%

6,6′-((1E,1′E)-(naphthalene-1,5-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol) (1280575-75-8) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) → 2Co(2+)*C10H6(NCHC6H3(OCH3)O)2(2-)*2H2O*2Cl(1-)=Co2(C10H6(NCHC6H3(OCH3)O)2)(H2O)2Cl2

Guidance literature:

In ethanol; soln. of Co salt (2 equiv.) in EtOH was added to soln. of ligand (1 equiv.) in EtOH; stirred at 80°C for 20 h; filtered; washed (cold EtOH); dried in vac. desiccator; elem. anal.;

DOI:10.1016/j.saa.2012.04.001

upstream raw materials:

3-methoxy-2-hydroxybenzaldehyde

1,5-naphthalenediamine

N,N'-bis(2-hydroxy-3-methoxybenzyliden)-1,5-diaminonaphthalene

Downstream raw materials:

N,N'-bis(2-hydroxy-3-methoxybenzyliden)-1,5-diaminonaphthalene