triethyl(4-aminophenylethynyl)silane

Base Information

• Chemical Name: triethyl(4-aminophenylethynyl)silane
• CAS No.: 1421764-15-9
• Molecular Formula: C₁₄H₂₁NSi
• Molecular Weight: 231.413
• Mol file: 1421764-15-9.mol

Synonyms:triethyl(4-aminophenylethynyl)silane

Chemical Property of triethyl(4-aminophenylethynyl)silane

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of triethyl(4-aminophenylethynyl)silane

There total 2 articles about triethyl(4-aminophenylethynyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

2-triethylsilylacetylene (1777-03-3) + p-aminoiodobenzene (540-37-4) → triethyl(4-aminophenylethynyl)silane (1421764-15-9)

Guidance literature:

2-triethylsilylacetylene; p-aminoiodobenzene; In tetrahydrofuran; for 0.5h; Inert atmosphere;

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; for 0.0833333h; Inert atmosphere;

With copper(l) iodide; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

DOI:10.1021/cm303844v

Reference yield: 51.0%

triethylsilane (617-86-7) + 4-Ethynylaniline (14235-81-5) → triethyl(4-aminophenylethynyl)silane (1421764-15-9) + C14H23NSi + C20H35NSi2

Guidance literature:

With oxygen; In toluene; at 100 ℃; for 12h; under 760.051 Torr;

DOI:10.1002/anie.201300988

Reference yield:

triethyl(4-aminophenylethynyl)silane (1421764-15-9) → C14H21NSi*BF4(1-)*H(1+)

Guidance literature:

With tetrafluoroboric acid; sodium nitrite;

DOI:10.1021/cm303844v

upstream raw materials:

2-triethylsilylacetylene

p-aminoiodobenzene

triethylsilane

4-Ethynylaniline