(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II)dichloride

Base Information

• Chemical Name: (3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II)dichloride
• CAS No.: 250220-36-1
• Molecular Formula: C51H76 Cl2 P2 Ru
• Molecular Weight: 923.088
• Hs Code.: 28439000
• European Community (EC) Number: 480-140-0,664-488-2
• Mol file: 250220-36-1.mol

Synonyms:250220-36-1;(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II)dichloride;dichloro-(3-phenylinden-1-ylidene)ruthenium;tricyclohexylphosphane;(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(IV) Dichloride;(SP-5-31)-Dichloro(3-phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(IV) DICHLORIDE;(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II) Dichloride;1H-imidazol-2-ylboronicacid;SCHEMBL727947;UZAFZWUWHHFWOK-UHFFFAOYSA-L;MFCD07369034;AKOS015900178;(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM DICHLORIDE;D92178;A852774;J-015778;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(II) DICHLORIDE;Bis(tricyclohexylphoshine)-3-phenyl-1H-inden-1-ylideneruthenium(IV) dichloride, Neolyst(TM) M1

Chemical Property of (3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II)dichloride

Chemical Property:

• Vapor Pressure: 9.7E-06mmHg at 25°C
• Melting Point: 120-141°C
• Boiling Point: 383.4oC at 760 mmHg
• Flash Point: 195.6oC
• PSA: 27.18000
• LogP: 17.51350
• Storage Temp.: 2-8°C
• Water Solubility.: Insoluble in water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 922.384272
• Heavy Atom Count: 56
• Complexity: 578

Purity/Quality:

95% ^*data from raw suppliers

(SP-5-31)-Dichloro(3-phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xn
• Hazard Codes: F,Xn
• Statements: 36/37/38-40-11
• Safety Statements: 26-36/37/39-36/37-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C1=CC=C(C=C1)C2=CC(=[Ru](Cl)Cl)C3=CC=CC=C32
• Uses: (3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)rutheniuM(IV) Dichloride is used in cross-metathesis reactions as a catalyst involving the involving the petrochemical and biodiesel industries. Metathesis Catalyst

Technology Process of (3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II)dichloride

There total 3 articles about (3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II)dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

ruthenium(III) chloride trihydrate + 1,1-diphenyl-2-propyn-1-ol (3923-52-2) + tricyclohexylphosphine (2622-14-2) → dichloro(3-phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II) (250220-36-1)

Guidance literature:

ruthenium(III) chloride trihydrate; With triphenylphosphine; In methanol; for 4h; Inert atmosphere; Schlenk technique; Reflux;

1,1-diphenyl-2-propyn-1-ol; With hydrogenchloride; In tetrahydrofuran; 1,4-dioxane; for 0.5h; Inert atmosphere; Schlenk technique; Reflux;

tricyclohexylphosphine; In tetrahydrofuran; 1,4-dioxane; acetone; at -20 - 20 ℃; for 10.5h; Solvent; Inert atmosphere; Schlenk technique;

DOI:10.3762/bjoc.15.73

Reference yield: 88.0%

dichloro(3-phenyl-1H-indene-1-ylidene)(bistriphenylphosphine)ruthenium(II) + tricyclohexylphosphine (2622-14-2) → dichloro(3-phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II) (250220-36-1)

Guidance literature:

In tetrahydrofuran; at 40 - 65 ℃; for 1h; Concentration; Time; Inert atmosphere;

Reference yield: 44.0%

→ dichloro(3-phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II) (250220-36-1)

Guidance literature:

In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

upstream raw materials:

tricyclohexylphosphine

1,1-diphenyl-2-propyn-1-ol