Ru(CO)ClH(PCy₃)2

Base Information

• Chemical Name: Ru(CO)ClH(PCy₃)2
• CAS No.: 36621-70-2
• Molecular Formula: C₃₇H₆₇ClOP₂Ru
• Molecular Weight: 726.409
• Mol file: 36621-70-2.mol

Synonyms:

Chemical Property of Ru(CO)ClH(PCy₃)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(CO)ClH(PCy₃)2

There total 21 articles about Ru(CO)ClH(PCy₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

ruthenium trichloride hydrate (14898-67-0) + tricyclohexylphosphine (2622-14-2) → carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) (36621-70-2,40935-25-9)

Guidance literature:

With triethylamine; In further solvent(s); RuCl3 dissolving in methoxyethanol, PCy3 addn. after 5 min, reflux (20 min), Et3N addn., reflux (6 h); cooling, filtration, washing (toluene), drying (vac.);

DOI:10.1016/S1381-1169(97)00102-7

Reference yield: 80.0%

methanol (67-56-1) + ruthenium(III) chloride trihydrate (14898-67-0) + tricyclohexylphosphine (2622-14-2) → carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) (36621-70-2,40935-25-9)

Guidance literature:

In methanol; N2-atmosphere; refluxing Ru-complex with excess of PCy3 for 2 h; crystn. on cooling to room temp., collection, washing (MeOH, Et2O), drying (vac.); elem. anal.; other unidentified products;

DOI:10.1021/ic00123a006

Reference yield: 73.0%

Grubbs catalyst first generation → carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) (36621-70-2,40935-25-9)

Guidance literature:

With propan-1-ol; triethylamine; In toluene; N2; addn. of 1-propanol, triethylamine to toluene soln. of the complex, heating at 75°C overnight; cooling to room temp., pptn. by addn. of methanol, stirring for 1 h, filtration, washing with methanol, hexanes, drying in vac.;

DOI:10.1021/om0208218

upstream raw materials:

ruthenium trichloride hydrate

tricyclohexylphosphine

methanol

ruthenium(III) chloride trihydrate

Downstream raw materials:

[RuCl₂(CO)(PCy₃)₂]

RuH(CO)(S₂CP(C₆H₁₁)3)(P(C₆H₁₁)3)2⁽¹⁺⁾*B(C₆H₅)4^(1-)=RuH(CO)(S₂CP(C₆H₁₁)3)(P(C₆H₁₁)3)2B(C₆H₅)4

trans,cis-RuHCl(PCy₃)₂(CO)₂

tris(cyclohexyl)phosphonium tetrafluoroborate