(D)-ortho-trifluoromethylstyrene oxide

Base Information

• Chemical Name: (D)-ortho-trifluoromethylstyrene oxide
• CAS No.: 1251070-14-0
• Molecular Formula: C₉H₇F₃O
• Molecular Weight: 189.141
• Mol file: 1251070-14-0.mol

Synonyms:(D)-ortho-trifluoromethylstyrene oxide

Chemical Property of (D)-ortho-trifluoromethylstyrene oxide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of (D)-ortho-trifluoromethylstyrene oxide

There total 2 articles about (D)-ortho-trifluoromethylstyrene oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

(+/-)-2-((2-trifluoromethyl)phenyl)oxirane (111991-15-2) → (D)-ortho-trifluoromethylstyrene oxide (1251070-14-0)

Guidance literature:

(+/-)-2-((2-trifluoromethyl)phenyl)oxirane; With sec.-butyllithium; (-)-sparteine; In cyclohexane; at -78 ℃; for 0.5h; Inert atmosphere;

With deuteromethanol; In tetrahydrofuran; cyclohexane; at -78 ℃; for 0.25h; Reagent/catalyst; Solvent; Time; Temperature; Inert atmosphere;

DOI:10.1039/c3cc40988k

Reference yield:

(R)-ortho-trifluoromethylstyrene oxide (663904-55-0) → (D)-ortho-trifluoromethylstyrene oxide (1251070-14-0)

Guidance literature:

(R)-ortho-trifluoromethylstyrene oxide; With sec.-butyllithium; In tetrahydrofuran; diethyl ether; cyclohexane; at -116.16 ℃; for 0.00194444h; Inert atmosphere;

With deuteromethanol; In tetrahydrofuran; diethyl ether; cyclohexane; at -116.16 - 19.84 ℃; Inert atmosphere;

DOI:10.1002/chem.201000897

upstream raw materials:

(R)-ortho-trifluoromethylstyrene oxide

(+/-)-2-((2-trifluoromethyl)phenyl)oxirane