(5Z)-7-<3-endo-<(phenylsulfonyl)amino>bicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester

Base Information

Chemical Name:(5Z)-7-<3-endo-<(phenylsulfonyl)amino>bicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester
CAS No.:115266-77-8
Molecular Formula:C₂₁H₂₉NO₄S
Molecular Weight:391.532
Hs Code.:

Synonyms:(5Z)-7-<3-endo-<(phenylsulfonyl)amino>bicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester

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Chemical Property of (5Z)-7-<3-endo-<(phenylsulfonyl)amino>bicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester

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Technology Process of (5Z)-7-<3-endo-<(phenylsulfonyl)amino>bicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester

There total 25 articles about (5Z)-7-<3-endo-<(phenylsulfonyl)amino>bicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: methyl (5Z)-7-<3-endo-<<(4-iodophenyl)sulfonyl>amino>bicyclo<2.2.1>hept-2-exo-yl>heptenoate

: 115266-77-8
(5Z)-7-<3-endo-<(phenylsulfonyl)amino>bicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester

Guidance literature:: With methanol; sodium tetrahydroborate; copper dichloride; at 0 ℃; for 0.5h;
DOI:10.1021/jo00283a025

Reference yield: 86.2%

: 98-09-9
benzenesulfonyl chloride

: 115266-76-7
(5Z)-7-<3-endo-aminobicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester trifluoroacetate

: 115266-77-8
(5Z)-7-<3-endo-<(phenylsulfonyl)amino>bicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester

Guidance literature:: With triethylamine; In dichloromethane; at 23 ℃; for 0.25h;
DOI:10.1021/jm00117a028

Reference yield:

: 17814-85-6
(4-carboxybutyl)triphenylphosphonium bromide

: 115266-77-8
(5Z)-7-<3-endo-<(phenylsulfonyl)amino>bicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: dimsylsodium / dimethylsulfoxide / 4 h / 25 °C

2: 2.8 g / diethyl ether

3: 99.6 percent / various solvent(s) / 3 h / 45 °C

4: 86.2 percent / triethylamine / CH₂Cl₂ / 0.25 h / 23 °C

With dimsylsodium; triethylamine; In diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jm00117a028