C₃₉H₇₃ClSi₂O₉SO₂C₆H₄(C₃H₆)3

Base Information

Chemical Name:C₃₉H₇₃ClSi₂O₉SO₂C₆H₄(C₃H₆)3
CAS No.:503609-67-4
Molecular Formula:C₅₄H₉₅ClO₁₁SSi₂
Molecular Weight:1044.03
Hs Code.:

C<sub>39</sub>H<sub>73</sub>ClSi<sub>2</sub>O<sub>9</sub>SO<sub>2</sub>C<sub>6</sub>H<sub>4</sub>(C<sub>3</sub>H<sub>6</sub>)3

Synonyms:C₃₉H₇₃ClSi₂O₉SO₂C₆H₄(C₃H₆)3

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Chemical Property of C₃₉H₇₃ClSi₂O₉SO₂C₆H₄(C₃H₆)3

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Technology Process of C₃₉H₇₃ClSi₂O₉SO₂C₆H₄(C₃H₆)3

There total 21 articles about C₃₉H₇₃ClSi₂O₉SO₂C₆H₄(C₃H₆)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 6553-96-4
2,4,6-triisopropylphenylsulfonyl chloride

: 503609-66-3
6-{[4-(tert-butyl-dimethyl-silanyloxy)-6-(4-hydroxy-butyl)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-triethylsilanyloxy-methyl}-2-(7-chloro-4-hydroxy-2-methylene-octa-5,7-dienyl)-5-methyl-tetrahydro-pyran-3,4-diol

: 503609-67-4
C₃₉H₇₃ClSi₂O₉SO₂C₆H₄(C₃H₆)3

Guidance literature:: With dmap; 2,6-di-tert-butyl-4-methylpyridine; In dichloromethane; at 0 ℃; for 3.16667h;
DOI:10.1021/ol034037a

Reference yield:

: 200186-27-2
(4R,5S,6S)-4-(4-Benzyloxy-butyl)-6-[1,3]dithian-2-ylmethyl-2,2,5-trimethyl-[1,3]dioxane

: 503609-67-4
C₃₉H₇₃ClSi₂O₉SO₂C₆H₄(C₃H₆)3

Guidance literature:: Multi-step reaction with 13 steps

1.1: n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / 0.67 h / -78 - -50 °C

1.2: CeCl₃ / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / 2.5 h / -78 °C

1.3: 51 percent / ZnCl₂ / tetrahydrofuran; diethyl ether; hexamethylphosphoric acid triamide / 4 h / -78 °C

2.1: 86 percent / 10-camphorsulfonic acid; H₂O / methanol / 2.5 h / 20 °C

3.1: 95 percent / Hg(ClO₄)2*4H₂O; CaCO₃; H₂O / acetonitrile / 0.42 h / 0 °C

4.1: 2,6-lutidine / 0.5 h / 20 °C

4.2: 90 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

5.1: 81 percent / 2,6-lutidine; 1-methyl-1,4-cyclohexadiene / Pd/C / methanol / 0.58 h / 20 - 45 °C

6.1: 85 percent / pyridinium p-toluenesulfonate; trimethyl orthoformate / CH₂Cl₂; methanol / 2.83 h / 0 °C

7.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / 20 °C

7.2: 86 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

8.1: 74 percent / H₂ / Pd/C / ethyl acetate / 2 h / 25858.1 Torr

9.1: pyridine / CH₂Cl₂ / 2 h / 0 °C

10.1: 51 percent / LDA / hexamethylphosphoric acid triamide; tetrahydrofuran; heptane / 2 h / -50 - -20 °C

11.1: dimethyldioxirane / CH₂Cl₂; acetone / 0.25 h / 0 °C

11.2: 77 percent / tributyltin triflate / CH₂Cl₂ / 0.33 h / -78 °C

12.1: 76 percent / KF / methanol; tetrahydrofuran / 26 h / 20 °C

13.1: 93 percent / 2,6-di-tert-butyl-4-methylpyridine; DMAP / CH₂Cl₂ / 3.17 h / 0 °C

With pyridine; 2,6-dimethylpyridine; dmap; potassium fluoride; n-butyllithium; 2,6-di-tert-butyl-4-methylpyridine; mercury(II) perchlorate; 2,5-dihydrotoluene; (1S)-10-camphorsulfonic acid; water; hydrogen; 3,3-dimethyldioxirane; pyridinium p-toluenesulfonate; calcium carbonate; lithium diisopropyl amide; trimethyl orthoformate; palladium on activated charcoal; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; n-heptane; dichloromethane; ethyl acetate; acetone; acetonitrile;
DOI:10.1021/ol034037a

Reference yield:

: 160797-23-9
(1R,2S)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2-methyl-but-3-en-1-ol

: 503609-67-4
C₃₉H₇₃ClSi₂O₉SO₂C₆H₄(C₃H₆)3

Guidance literature:: Multi-step reaction with 20 steps

1.1: NaH / tetrahydrofuran / 0.5 h / 20 °C

1.2: tetrabutylammonium iodide / 36 h / 20 °C

2.1: 10-camphorsulfonic acid / methanol; H₂O / 20 °C

3.1: 86 percent / Et₃N; DMAP / CH₂Cl₂ / 20 °C

4.1: 93 percent / TfOH / diethyl ether

5.1: (DHQD)2PYR; K₃Fe(CN)6; aq. K₂CO₃ / K₂OsO₂(OH)4 / 2-methyl-propan-2-ol / 0 °C

6.1: NaOMe

7.1: 95 percent / SO₃*Pyr; DMSO / CH₂Cl₂ / 0 °C

8.1: n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / 0.67 h / -78 - -50 °C

8.2: CeCl₃ / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / 2.5 h / -78 °C

8.3: 51 percent / ZnCl₂ / tetrahydrofuran; diethyl ether; hexamethylphosphoric acid triamide / 4 h / -78 °C

9.1: 86 percent / 10-camphorsulfonic acid; H₂O / methanol / 2.5 h / 20 °C

10.1: 95 percent / Hg(ClO₄)2*4H₂O; CaCO₃; H₂O / acetonitrile / 0.42 h / 0 °C

11.1: 2,6-lutidine / 0.5 h / 20 °C

11.2: 90 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

12.1: 81 percent / 2,6-lutidine; 1-methyl-1,4-cyclohexadiene / Pd/C / methanol / 0.58 h / 20 - 45 °C

13.1: 85 percent / pyridinium p-toluenesulfonate; trimethyl orthoformate / CH₂Cl₂; methanol / 2.83 h / 0 °C

14.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / 20 °C

14.2: 86 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

15.1: 74 percent / H₂ / Pd/C / ethyl acetate / 2 h / 25858.1 Torr

16.1: pyridine / CH₂Cl₂ / 2 h / 0 °C

17.1: 51 percent / LDA / hexamethylphosphoric acid triamide; tetrahydrofuran; heptane / 2 h / -50 - -20 °C

18.1: dimethyldioxirane / CH₂Cl₂; acetone / 0.25 h / 0 °C

18.2: 77 percent / tributyltin triflate / CH₂Cl₂ / 0.33 h / -78 °C

19.1: 76 percent / KF / methanol; tetrahydrofuran / 26 h / 20 °C

20.1: 93 percent / 2,6-di-tert-butyl-4-methylpyridine; DMAP / CH₂Cl₂ / 3.17 h / 0 °C

With pyridine; 2,6-dimethylpyridine; dmap; potassium fluoride; n-butyllithium; 2,6-di-tert-butyl-4-methylpyridine; mercury(II) perchlorate; hydroquinindine-2,5-diphenyl-4,6-pyrimidinediyl diether; 2,5-dihydrotoluene; pyridine-SO₃ complex; trifluorormethanesulfonic acid; (1S)-10-camphorsulfonic acid; water; hydrogen; sodium methylate; 3,3-dimethyldioxirane; pyridinium p-toluenesulfonate; sodium hydride; potassium carbonate; dimethyl sulfoxide; triethylamine; calcium carbonate; potassium hexacyanoferrate(III); lithium diisopropyl amide; trimethyl orthoformate; palladium on activated charcoal; potassium dioxotetrahydroxoosmate(VI); In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; hexane; n-heptane; dichloromethane; water; ethyl acetate; acetone; acetonitrile; tert-butyl alcohol; 5.1: Sharpless asymmetric dihydroxylation / 7.1: Parikh-Doering oxidation;
DOI:10.1021/ol034037a