6-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5,5-dimethyl-cyclohex-2-enone

Base Information

Chemical Name:6-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5,5-dimethyl-cyclohex-2-enone
CAS No.:189511-37-3
Molecular Formula:C₁₈H₃₄O₂Si
Molecular Weight:310.552
Hs Code.:

Synonyms:6-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5,5-dimethyl-cyclohex-2-enone

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Chemical Property of 6-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5,5-dimethyl-cyclohex-2-enone

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Technology Process of 6-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5,5-dimethyl-cyclohex-2-enone

There total 5 articles about 6-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5,5-dimethyl-cyclohex-2-enone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

: 4694-17-1
5,5-dimethlycyclohex-2-en-1-one

: 134510-70-6
(S)-3-(tert-butyldimethylsilyloxy)-1-butyl iodide

: 189511-37-3
6-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5,5-dimethyl-cyclohex-2-enone

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1016/S0957-4166(97)00055-4

Reference yield:

: 6267-39-6
3-ethoxy-5,5-dimethyl-2-cyclohexen-1-one

: 189511-37-3
6-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5,5-dimethyl-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: LDA / tetrahydrofuran / -78 - 20 °C

2: H₂ / 5percent Rh/alumina / ethyl acetate / 4940 Torr

3: NaH / tetrahydrofuran / Ambient temperature

With hydrogen; sodium hydride; lithium diisopropyl amide; Rh/Al₂O₃; In tetrahydrofuran; ethyl acetate;
DOI:10.1016/S0957-4166(97)00055-4

Reference yield:

: 134510-70-6
(S)-3-(tert-butyldimethylsilyloxy)-1-butyl iodide

: 189511-37-3
6-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5,5-dimethyl-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: LDA / tetrahydrofuran / -78 - 20 °C

2: H₂ / 5percent Rh/alumina / ethyl acetate / 4940 Torr

3: NaH / tetrahydrofuran / Ambient temperature

With hydrogen; sodium hydride; lithium diisopropyl amide; Rh/Al₂O₃; In tetrahydrofuran; ethyl acetate;
DOI:10.1016/S0957-4166(97)00055-4