8-C₆H₅-nido-7,8,9-C₃B₈H₁₁

Base Information

• Chemical Name: 8-C₆H₅-nido-7,8,9-C₃B₈H₁₁
• CAS No.: 1353051-78-1
• Molecular Formula: C₉H₁₆B₈
• Molecular Weight: 210.714
• Mol file: 1353051-78-1.mol

Synonyms:8-C₆H₅-nido-7,8,9-C₃B₈H₁₁

Chemical Property of 8-C₆H₅-nido-7,8,9-C₃B₈H₁₁

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 8-C₆H₅-nido-7,8,9-C₃B₈H₁₁

There total 3 articles about 8-C₆H₅-nido-7,8,9-C₃B₈H₁₁ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[Et4N][8-C6H5-7,8,9-C3B8H10] → 8-C6H5-nido-7,8,9-C3B8H11 (1353051-78-1)

Guidance literature:

With sulfuric acid; In dichloromethane; at 0 - 20 ℃; for 1h;

DOI:10.1002/chem.201102016

Reference yield:

benzoyl chloride (98-88-4) → 8-C6H5-nido-7,8,9-C3B8H11 (1353051-78-1)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydride; triethylamine / dichloromethane / 24.5 h / -40 °C / Reflux

2: sulfuric acid / dichloromethane / 1 h / 0 - 20 °C

With sulfuric acid; sodium hydride; triethylamine; In dichloromethane;

DOI:10.1002/chem.201102016

Reference yield:

sulfuric acid (7664-93-9) + arachno-6,9-C2B8H14 + benzoyl chloride (98-88-4) → 8-C6H5-nido-7,8,9-C3B8H11 (1353051-78-1)

Guidance literature:

arachno-6,9-C₂B₈H₁₄; benzoyl chloride; With N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; at 0 ℃; for 24.5h; Inert atmosphere; Reflux;

sulfuric acid; at 0 ℃; Inert atmosphere;

DOI:10.1021/ic401293g

upstream raw materials:

benzoyl chloride

sulfuric acid