tert-Butyl-((1S,2R,4S,5R,6S)-4-methoxy-5-methyl-3,7-dioxa-bicyclo[4.1.0]hept-2-ylmethoxy)-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-((1S,2R,4S,5R,6S)-4-methoxy-5-methyl-3,7-dioxa-bicyclo[4.1.0]hept-2-ylmethoxy)-diphenyl-silane
CAS No.:220094-49-5
Molecular Formula:C₂₄H₃₂O₄Si
Molecular Weight:412.601
Hs Code.:

Synonyms:tert-Butyl-((1S,2R,4S,5R,6S)-4-methoxy-5-methyl-3,7-dioxa-bicyclo[4.1.0]hept-2-ylmethoxy)-diphenyl-silane

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Chemical Property of tert-Butyl-((1S,2R,4S,5R,6S)-4-methoxy-5-methyl-3,7-dioxa-bicyclo[4.1.0]hept-2-ylmethoxy)-diphenyl-silane

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Technology Process of tert-Butyl-((1S,2R,4S,5R,6S)-4-methoxy-5-methyl-3,7-dioxa-bicyclo[4.1.0]hept-2-ylmethoxy)-diphenyl-silane

There total 9 articles about tert-Butyl-((1S,2R,4S,5R,6S)-4-methoxy-5-methyl-3,7-dioxa-bicyclo[4.1.0]hept-2-ylmethoxy)-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 101978-79-4
Methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-allopyranoside

: 220094-49-5
tert-Butyl-((1S,2R,4S,5R,6S)-4-methoxy-5-methyl-3,7-dioxa-bicyclo[4.1.0]hept-2-ylmethoxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: hydrogen / Pd/C / ethyl acetate

2.1: pyridine / ethyl acetate

3.1: CH₃C(OCH₃)3; TsOH

3.2: Et₃N; AcBr / CH₂Cl₂

3.3: NaOMe / methanol

With pyridine; Trimethyl orthoacetate; hydrogen; toluene-4-sulfonic acid; palladium on activated charcoal; In ethyl acetate;
DOI:10.1016/S0040-4039(02)00457-4

Reference yield:

: 121467-58-1
(2R,4aR,6S,7S,8aR)-6-Methoxy-7-methyl-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-one

: 220094-49-5
tert-Butyl-((1S,2R,4S,5R,6S)-4-methoxy-5-methyl-3,7-dioxa-bicyclo[4.1.0]hept-2-ylmethoxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1.1: NaBH₄ / methanol; dimethylformamide

2.1: hydrogen / Pd/C / ethyl acetate

3.1: pyridine / ethyl acetate

4.1: CH₃C(OCH₃)3; TsOH

4.2: Et₃N; AcBr / CH₂Cl₂

4.3: NaOMe / methanol

With pyridine; Trimethyl orthoacetate; sodium tetrahydroborate; hydrogen; toluene-4-sulfonic acid; palladium on activated charcoal; In methanol; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(02)00457-4

Reference yield:

: 68907-47-1
methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-altro-pyranoside

: 220094-49-5
tert-Butyl-((1S,2R,4S,5R,6S)-4-methoxy-5-methyl-3,7-dioxa-bicyclo[4.1.0]hept-2-ylmethoxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 5 steps

1.1: (COCl)2; DMSO; Et₃N / CH₂Cl₂

1.2: Et₃N / CH₂Cl₂; methanol

2.1: NaBH₄ / methanol; dimethylformamide

3.1: hydrogen / Pd/C / ethyl acetate

4.1: pyridine / ethyl acetate

5.1: CH₃C(OCH₃)3; TsOH

5.2: Et₃N; AcBr / CH₂Cl₂

5.3: NaOMe / methanol

With pyridine; Trimethyl orthoacetate; sodium tetrahydroborate; oxalyl dichloride; hydrogen; toluene-4-sulfonic acid; dimethyl sulfoxide; triethylamine; palladium on activated charcoal; In methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 1.1: Swern oxidation;
DOI:10.1016/S0040-4039(02)00457-4