C₃₄H₅₂I₃O₁₂S^(1-)*Na⁽¹⁺⁾

Base Information

• Chemical Name: C₃₄H₅₂I₃O₁₂S^(1-)*Na⁽¹⁺⁾
• CAS No.: 1234307-26-6
• Molecular Formula: C₃₄H₅₂I₃O₁₂S*Na
• Molecular Weight: 1088.55
• Mol file: 1234307-26-6.mol

Synonyms:C₃₄H₅₂I₃O₁₂S^(1-)*Na⁽¹⁺⁾

Chemical Property of C₃₄H₅₂I₃O₁₂S^(1-)*Na⁽¹⁺⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₄H₅₂I₃O₁₂S^(1-)*Na⁽¹⁺⁾

There total 10 articles about C₃₄H₅₂I₃O₁₂S^(1-)*Na⁽¹⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C52H94I3O12SSi3(1-)*Na(1+) (1234307-25-5) → C34H52I3O12S(1-)*Na(1+) (1234307-26-6)

Guidance literature:

With water; acetic acid; trifluoroacetic acid; In tetrahydrofuran; at 20 ℃; for 48h;

Reference yield:

1-O-allyl-α-D-glucopyranoside (7464-56-4,821794-45-0) → C34H52I3O12S(1-)*Na(1+) (1234307-26-6)

Guidance literature:

Multi-step reaction with 8 steps

1: dmap; pyridine / 16 h / 20 °C

2: 2,6-dimethylpyridine / dichloromethane / 16 h / Inert atmosphere

3: ethanol / 3 h / Reflux

4: trimethylamine-N-oxide; water / osmium(VIII) oxide / tert-butyl alcohol / 22 h / 20 °C

5: pyridine / dichloromethane / 2 h / 20 °C

6: dmap; 2,2'-dipyridyl carbonate / dichloromethane / 48 h / 20 °C

7: Oxone; potassium acetate; acetic acid / 24 h / 20 °C

8: trifluoroacetic acid; water; acetic acid / tetrahydrofuran / 48 h / 20 °C

With pyridine; 2,6-dimethylpyridine; dmap; Oxone; 2,2'-dipyridyl carbonate; trimethylamine-N-oxide; water; potassium acetate; acetic acid; trifluoroacetic acid; osmium(VIII) oxide; In tetrahydrofuran; ethanol; dichloromethane; tert-butyl alcohol;

Reference yield:

D-Glucose (2280-44-6) → C34H52I3O12S(1-)*Na(1+) (1234307-26-6)

Guidance literature:

Multi-step reaction with 10 steps

1.1: trifluorormethanesulfonic acid / 48 h / 0 - 80 °C

1.2: 4 h / 40 °C

2.1: water; acetic acid / 1 h / 100 °C

3.1: dmap; pyridine / 16 h / 20 °C

4.1: 2,6-dimethylpyridine / dichloromethane / 16 h / Inert atmosphere

5.1: ethanol / 3 h / Reflux

6.1: trimethylamine-N-oxide; water / osmium(VIII) oxide / tert-butyl alcohol / 22 h / 20 °C

7.1: pyridine / dichloromethane / 2 h / 20 °C

8.1: dmap; 2,2'-dipyridyl carbonate / dichloromethane / 48 h / 20 °C

9.1: Oxone; potassium acetate; acetic acid / 24 h / 20 °C

10.1: trifluoroacetic acid; water; acetic acid / tetrahydrofuran / 48 h / 20 °C

With pyridine; 2,6-dimethylpyridine; dmap; Oxone; 2,2'-dipyridyl carbonate; trimethylamine-N-oxide; trifluorormethanesulfonic acid; water; potassium acetate; acetic acid; trifluoroacetic acid; osmium(VIII) oxide; In tetrahydrofuran; ethanol; dichloromethane; tert-butyl alcohol;

upstream raw materials:

D-Glucose

1-O-allyl-α-D-glucopyranoside

1-O-(2-propenyl)-6-O-(4-tolylsulfonyl)-α-D-glucose

1-O-allyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-6-O-(4-tolylsulfonyl)-α-D-glucopyranoside