(C₅Me₅)2Th(NC(Me)(3,5-F₂-C₆H₃))2

Base Information

• Chemical Name: (C₅Me₅)2Th(NC(Me)(3,5-F₂-C₆H₃))2
• CAS No.: 937037-08-6
• Molecular Formula: C₃₆H₄₂F₄N₂Th
• Molecular Weight: 810.775
• Mol file: 937037-08-6.mol

Synonyms:(C₅Me₅)2Th(NC(Me)(3,5-F₂-C₆H₃))2

Chemical Property of (C₅Me₅)2Th(NC(Me)(3,5-F₂-C₆H₃))2

Chemical Property:

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Technology Process of (C₅Me₅)2Th(NC(Me)(3,5-F₂-C₆H₃))2

There total 1 articles about (C₅Me₅)2Th(NC(Me)(3,5-F₂-C₆H₃))2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

dimethylbis(η5-pentamethylcyclopentadienyl)thorium (67506-90-5) + 3,5-difluorobenzonitrile (64248-63-1) → (C5Me5)2Th(NC(Me)(3,5-F2-C6H3))2 (937037-08-6)

Guidance literature:

In toluene; dropwise addn. of soln. of nitrile in toluene to a stirred soln. of (C5Me5)2ThMe2 in toluene under inert atmosphere, stirring at room temp. for 14 h; removal of volatiles in vac., dissolution in pentane, hot filtration through Celite, isolation of product from filtrate, drying under reduced pressure;

DOI:10.1021/ja0686458

upstream raw materials:

dimethylbis(η5-pentamethylcyclopentadienyl)thorium

3,5-difluorobenzonitrile

Refernces