anti-7-((dicarbomethoxy)methyl)-endo-5-((4-phenylbenzoyl)oxy)bicyclo<2.2.1>heptan-2-one

Base Information

Chemical Name:anti-7-((dicarbomethoxy)methyl)-endo-5-((4-phenylbenzoyl)oxy)bicyclo<2.2.1>heptan-2-one
CAS No.:78592-03-7
Molecular Formula:C₂₅H₂₄O₇
Molecular Weight:436.461
Hs Code.:

Synonyms:anti-7-((dicarbomethoxy)methyl)-endo-5-((4-phenylbenzoyl)oxy)bicyclo<2.2.1>heptan-2-one

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Chemical Property of anti-7-((dicarbomethoxy)methyl)-endo-5-((4-phenylbenzoyl)oxy)bicyclo<2.2.1>heptan-2-one

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Technology Process of anti-7-((dicarbomethoxy)methyl)-endo-5-((4-phenylbenzoyl)oxy)bicyclo<2.2.1>heptan-2-one

There total 3 articles about anti-7-((dicarbomethoxy)methyl)-endo-5-((4-phenylbenzoyl)oxy)bicyclo<2.2.1>heptan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 78592-00-4
endo-3-((4-phenylbenzoyl)oxy)tricyclo<3.2.0.0^2,7>heptan-6-one

: 108-59-8
malonic acid dimethyl ester

: 78592-03-7
anti-7-((dicarbomethoxy)methyl)-endo-5-((4-phenylbenzoyl)oxy)bicyclo<2.2.1>heptan-2-one

Guidance literature:: With sodium methylate; In tetrahydrofuran; methanol; 1.) 50 deg C, 5 min, 2.) room temp., 2h;
DOI:10.1021/jo00333a021

Reference yield:

: 78592-05-9
exo-2-bromo-endo-3-((4-phenylbenzoyl)oxy)bicyclo<3.2.0>heptan-6-one

: 78592-03-7
anti-7-((dicarbomethoxy)methyl)-endo-5-((4-phenylbenzoyl)oxy)bicyclo<2.2.1>heptan-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / sodium hexamethyldisilazide / diethyl ether / 1.) -10 deg C, 2.) 0 deg C, 2h

2: 78 percent / NaOCH₃ / methanol; tetrahydrofuran / 1.) 50 deg C, 5 min, 2.) room temp., 2h

With sodium methylate; sodium hexamethyldisilazane; In tetrahydrofuran; methanol; diethyl ether;
DOI:10.1021/jo00333a021

Reference yield:

: 14002-51-8
4-biphenyl-carboxylic acid chloride

: 78592-03-7
anti-7-((dicarbomethoxy)methyl)-endo-5-((4-phenylbenzoyl)oxy)bicyclo<2.2.1>heptan-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: 77 percent / pyridine / 24 h / Ambient temperature

2: 75 percent / sodium hexamethyldisilazide / diethyl ether / 1.) -10 deg C, 2.) 0 deg C, 2h

3: 78 percent / NaOCH₃ / methanol; tetrahydrofuran / 1.) 50 deg C, 5 min, 2.) room temp., 2h

With sodium methylate; sodium hexamethyldisilazane; In tetrahydrofuran; pyridine; methanol; diethyl ether;
DOI:10.1021/jo00333a021