benzyl 2,3,4,6-tetra-O-acetyl-α-D-idopyranoside

Base Information

• Chemical Name: benzyl 2,3,4,6-tetra-O-acetyl-α-D-idopyranoside
• CAS No.: 1620782-22-0
• Molecular Formula: C₂₁H₂₆O₁₀
• Molecular Weight: 438.431
• Mol file: 1620782-22-0.mol

Synonyms:benzyl 2,3,4,6-tetra-O-acetyl-α-D-idopyranoside

Chemical Property of benzyl 2,3,4,6-tetra-O-acetyl-α-D-idopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl 2,3,4,6-tetra-O-acetyl-α-D-idopyranoside

There total 2 articles about benzyl 2,3,4,6-tetra-O-acetyl-α-D-idopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2,3,4,6-tetra-O-acetyl-α,β-D-idopyranosyl trichloroacetimidate + benzyl alcohol (100-51-6,185532-71-2) → benzyl 2,3,4,6-tetra-O-acetyl-α-D-idopyranoside (1620782-22-0)

Guidance literature:

2,3,4,6-tetra-O-acetyl-α,β-D-idopyranosyl trichloroacetimidate; benzyl alcohol; With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 0 ℃; for 0.333333h; Molecular sieve;

With triethylamine; In dichloromethane;

DOI:10.1002/ejoc.201402187

Reference yield: 83.0%

benzyl alcohol (100-51-6,185532-71-2) + 1,2,3,4,6,-penta-O-acetyl-α-D-idopyranose (16299-15-3) → benzyl 2,3,4,6-tetra-O-acetyl-α-D-idopyranoside (1620782-22-0)

Guidance literature:

benzyl alcohol; 1,2,3,4,6,-penta-O-acetyl-α-D-idopyranose; With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 4h; Molecular sieve;

With triethylamine; In dichloromethane;

DOI:10.1002/ejoc.201402187

Reference yield:

benzyl 2,3,4,6-tetra-O-acetyl-α-D-idopyranoside (1620782-22-0) → C13H18O6 (1620782-23-1)

Guidance literature:

With methanol; sodium methylate; for 1h;

DOI:10.1002/ejoc.201402187

upstream raw materials:

benzyl alcohol

1,2,3,4,6,-penta-O-acetyl-α-D-idopyranose

Downstream raw materials:

C₁₃H₁₈O₆

benzyl 2,3,4,6-tetra-O-benzoyl-α-D-idopyranoside

2,3,4,6-tetra-O-benzoyl-α-D-idopyranose

2,3,4,6-tetra-O-benzoyl-β-D-idopyranose