phenylcarbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester

Base Information

Chemical Name:phenylcarbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester
CAS No.:956484-60-9
Molecular Formula:C₂₀H₁₆F₁₇NO₂
Molecular Weight:625.325
Hs Code.:

Synonyms:phenylcarbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of phenylcarbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester

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Technology Process of phenylcarbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester

There total 3 articles about phenylcarbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 956484-57-4
carbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester

: 108-86-1,52753-63-6
bromobenzene

: 956484-60-9
phenylcarbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester

Guidance literature:: With caesium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; palladium diacetate; In 1,4-dioxane; at 100 ℃; for 24h;
DOI:10.1021/jo701573w

Reference yield: 65.0%

: 956484-57-4
carbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester

: 108-90-7
chlorobenzene

: 956484-60-9
phenylcarbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester

Guidance literature:: With caesium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; palladium diacetate; In 1,4-dioxane; at 100 ℃; for 24h;
DOI:10.1021/jo701573w

Reference yield:

: 2-[2-(1H,1H,2H,2H-perfluorodecyl)isopropoxycarbonyloxyimino]-2-phenylacetonitrile

: 956484-60-9
phenylcarbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / NH₃; Et₃N / CH₂Cl₂; methanol / 6 h / 20 °C

2: 79 percent / xantphos; Cs₂CO₃ / Pd(OAc)2 / dioxane / 24 h / 100 °C

With ammonia; caesium carbonate; triethylamine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; palladium diacetate; In 1,4-dioxane; methanol; dichloromethane; 2: Buchwald-Hartwig cross coupling;
DOI:10.1021/jo701573w