9-(Bromomethyl)phenanthrene

Base Information

• Chemical Name: 9-(Bromomethyl)phenanthrene
• CAS No.: 24471-57-6
• Molecular Formula: C15H11 Br
• Molecular Weight: 271.156
• DSSTox Substance ID: DTXSID50179235
• Nikkaji Number: J2.973.976E
• Wikidata: Q83049737
• Mol file: 24471-57-6.mol

Synonyms:9-(Bromomethyl)phenanthrene;24471-57-6;Phenanthrene, 9-(bromomethyl)-;SCHEMBL1294408;DTXSID50179235

Chemical Property of 9-(Bromomethyl)phenanthrene

Chemical Property:

• Vapor Pressure: 1.3E-06mmHg at 25°C
• Boiling Point: 411.7°Cat760mmHg
• Flash Point: 209°C
• Density: 1.448g/cm³
• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 270.00441
• Heavy Atom Count: 16
• Complexity: 238

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=C(C3=CC=CC=C23)CBr

Technology Process of 9-(Bromomethyl)phenanthrene

There total 13 articles about 9-(Bromomethyl)phenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

9-methylphenanthrene (883-20-5) → 9-bromomethylphenantrene (24471-57-6)

Guidance literature:

With N-Bromosuccinimide; Perbenzoic acid; In benzene; Heating; overnight;

Reference yield: 93.0%

9-hydroxymethylphenanthrene (4707-72-6) → 9-bromomethylphenantrene (24471-57-6)

Guidance literature:

With phosphorus tribromide; In toluene; at 0 - 20 ℃; for 1h;

DOI:10.1021/acs.inorgchem.7b01472

Reference yield: 87.0%

9-methylene-9,10-dihydrophenanthrene (82491-33-6) → 9-bromomethylphenantrene (24471-57-6)

Guidance literature:

With bromine; In tetrachloromethane;

DOI:10.1039/P19880002579

upstream raw materials:

9-methylphenanthrene

9-hydroxymethylphenanthrene

1a,9b-dihydro-cyclopropa[1]phenanthrene

9-methylene-9,10-dihydrophenanthrene

Downstream raw materials:

9-(cyanomethyl)phenanthrene

N-(9-phenanthrylmethyl)-L-phenylalanine methyl ester

2-(9-phenanthrylmethyl)cyclohexanone

2-(9-phenanthrylmethyl)phenol

Refernces

• 1、 Zhu, Xiaolin,Cui, Peng,Kilina, Svetlana,Sun, Wenfang. "Multifunctional Cationic Iridium(III) Complexes Bearing 2-Aryloxazolo[4,5-f][1,10]phenanthroline (N^N) Ligand: Synthesis, Crystal Structure, Photophysics, Mechanochromic/Vapochromic Effects, and Reverse Saturable Absorption". . p. 13715 - 13731. Retrieved 2017.
• 2、 Fujino, Shota,Yamaji, Minoru,Okamoto, Hideki,Mutai, Toshiki,Yoshikawa, Isao,Houjou, Hirohiko,Tani, Fumito. "Systematic investigations on fused π-system compounds of seven benzene rings prepared by photocyclization of diphenanthrylethenes". . p. 925 - 934. Retrieved 2017/07/10.