2-[(E)-Styryl]benzo[c]phenanthrene

Base Information

Chemical Name:2-[(E)-Styryl]benzo[c]phenanthrene
CAS No.:32829-04-2
Molecular Formula:C₂₆H₁₈
Molecular Weight:330.429
Hs Code.:
NSC Number:249205
DSSTox Substance ID:DTXSID10421242
Nikkaji Number:J2.892.838F
Wikidata:Q82232653

Synonyms:NSC249205;32829-04-2;2-[(E)-Styryl]benzo[c]phenanthrene;DTXSID10421242;QUSCSNXGRSOOHC-ZHACJKMWSA-N;NSC-249205;1-Phenyl-2-(2-benzo[c]phenathryl)ethylene, trans

Suppliers and Price of 2-[(E)-Styryl]benzo[c]phenanthrene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of 2-[(E)-Styryl]benzo[c]phenanthrene

Chemical Property:

Vapor Pressure:7.11E-12mmHg at 25°C
XLogP3:7.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:330.140850574
Heavy Atom Count:26
Complexity:484

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)C=CC2=CC3=C(C=CC4=C3C5=CC=CC=C5C=C4)C=C2
Isomeric SMILES:C1=CC=C(C=C1)/C=C/C2=CC3=C(C=CC4=C3C5=CC=CC=C5C=C4)C=C2

Technology Process of 2-[(E)-Styryl]benzo[c]phenanthrene

There total 4 articles about 2-[(E)-Styryl]benzo[c]phenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 53034-15-4
2-bromobenzophenanthrene

: 32829-04-2
2-styrylbenzo[c]phenanthrene

Guidance literature:: With 1,3-bis-(diphenylphosphino)propane; palladium diacetate; In N,N-dimethyl acetamide; at 20 ℃; Inert atmosphere;

styrene; 2-bromobenzophenanthrene; With tetrabutylammomium bromide; potassium carbonate; In N,N-dimethyl acetamide; at 100 - 140 ℃; Inert atmosphere;
DOI:10.3998/ark.5550190.0012.902

Reference yield:

: 53034-14-3
(E)-1-(4-bromophenyl)-2-(2-naphthyl)ethylene

: 32829-04-2
2-styrylbenzo[c]phenanthrene

Guidance literature:: Multi-step reaction with 2 steps

1.1: iodine / tetrahydrofuran; toluene / 20 h / Irradiation

2.1: 1,3-bis-(diphenylphosphino)propane; palladium diacetate / N,N-dimethyl acetamide / 20 °C / Inert atmosphere

2.2: 100 - 140 °C / Inert atmosphere

With 1,3-bis-(diphenylphosphino)propane; iodine; palladium diacetate; In tetrahydrofuran; N,N-dimethyl acetamide; toluene; 2.2: Mizoroki-Heck reaction;
DOI:10.3998/ark.5550190.0012.902

Reference yield:

: 51044-13-4
4-bromobenzyl triphenylphosphonium bromide

: 32829-04-2
2-styrylbenzo[c]phenanthrene

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium methylate / methanol / 24 h / 20 °C / Inert atmosphere

2.1: iodine / tetrahydrofuran; toluene / 20 h / Irradiation

3.1: 1,3-bis-(diphenylphosphino)propane; palladium diacetate / N,N-dimethyl acetamide / 20 °C / Inert atmosphere

3.2: 100 - 140 °C / Inert atmosphere

With 1,3-bis-(diphenylphosphino)propane; iodine; sodium methylate; palladium diacetate; In tetrahydrofuran; methanol; N,N-dimethyl acetamide; toluene; 1.1: Wittig reaction / 3.2: Mizoroki-Heck reaction;
DOI:10.3998/ark.5550190.0012.902