(S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1S,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-one

Base Information

Chemical Name:(S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1S,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-one
CAS No.:1006380-60-4
Molecular Formula:C₄₇H₅₈O₄Si₂
Molecular Weight:743.146
Hs Code.:

(S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1S,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-one

Synonyms:(S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1S,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-one

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Chemical Property of (S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1S,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-one

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Technology Process of (S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1S,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-one

There total 17 articles about (S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1S,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1006380-54-6
(1S,2S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1R,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-ol

: 1006380-60-4
(S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1S,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-one

Guidance literature:: With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; for 0.25h;
DOI:10.1021/ol7027338

Reference yield: 95.0%

: 1006380-55-7
(1R,2S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1R,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-ol

: 1006380-60-4
(S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1S,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-one

Guidance literature:: With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; for 0.25h; Inert atmosphere;
DOI:10.1002/chem.201200257

Reference yield:

: 1006380-52-4
(1S,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-enecarbaldehyde

: 1006380-60-4
(S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-1-((1S,2S,5S,6S)-5-((dimethyl(phenyl)silyl)methyl)-6-((4-methoxybenzyl)oxy)-2-vinylcyclohex-3-en-1-yl)but-3-en-1-one

Guidance literature:: Multi-step reaction with 2 steps

1: chromium dichloride / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere

2: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.25 h / Inert atmosphere

With chromium dichloride; sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; N,N-dimethyl-formamide; 1: Hiyama-Nozaki-Kishi reaction;
DOI:10.1002/chem.201200257