dibromo[bis(trifluoromethyl)]germane

Base Information

• Chemical Name: dibromo[bis(trifluoromethyl)]germane
• CAS No.: 56593-16-9
• Molecular Formula: C2Br2 F6 Ge
• Molecular Weight: 370.4598
• Mol file: 56593-16-9.mol

Synonyms:Bis(trifluoromethyl)germanium dibromide

Chemical Property of dibromo[bis(trifluoromethyl)]germane

Chemical Property:

• Vapor Pressure: 149mmHg at 25°C
• Boiling Point: 68.9°Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dibromo[bis(trifluoromethyl)]germane

There total 4 articles about dibromo[bis(trifluoromethyl)]germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

germanium tetrabromide (13450-92-5) + bis(trifluoromethyl)mercury (371-76-6) → bis-(trifluoro methyl) dibromo germane (56593-16-9) + tris-(trifluoro methyl) bromo germane (65094-18-0)

Guidance literature:

2:1 molar ratio of (CF3)2Hg to GeBr4; 150°C, 24 h;

DOI:10.1021/ja00474a013

Reference yield: 55.0%

germanium tetrabromide (13450-92-5) + bis(trifluoromethyl)mercury (371-76-6) → (trifluoro methyl) tribromo germane (56593-15-8) + bis-(trifluoro methyl) dibromo germane (56593-16-9) + tris-(trifluoro methyl) bromo germane (65094-18-0)

Guidance literature:

at 110°C (18 h); equimol. mixt. of educts; sealed tube;

DOI:10.1016/S0022-1139(00)83109-7

Reference yield:

silver(I) bromide + perfluormethylgermanium iodide (754-36-9) → bis-(trifluoro methyl) dibromo germane (56593-16-9)

Guidance literature:

addition of an excess of AgBr;;

upstream raw materials:

perfluormethylgermanium iodide

germanium tetrabromide

bis(trifluoromethyl)mercury