Bis(trifluoromethyl)mercury

Base Information

• Chemical Name: Bis(trifluoromethyl)mercury
• CAS No.: 371-76-6
• Molecular Formula: C2F6 Hg
• Molecular Weight: 338.602
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID30993173
• Mol file: 371-76-6.mol

Synonyms:Bis(trifluoromethyl)mercury;371-76-6;di(Trifluoromethyl)mercury;Mercury, bis(trifluoromethyl)-;SCHEMBL4143353;DTXSID30993173;MFCD00042516;AKOS015955368;7238-80-4

Chemical Property of Bis(trifluoromethyl)mercury

Chemical Property:

• PSA: 0.00000
• LogP: 2.94830
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 339.961063
• Heavy Atom Count: 9
• Complexity: 76.2

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(F)(F)(F)[Hg]C(F)(F)F

Technology Process of Bis(trifluoromethyl)mercury

There total 7 articles about Bis(trifluoromethyl)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

bis(trifluoromethyl)phenylthallium (121029-71-8) + mercury → trifluoromethan (75-46-7) + bis(trifluoromethyl)mercury (371-76-6) + phenyl(trifluoromethyl)mercury (24925-18-6)

Guidance literature:

In further solvent(s); Placing of starting materials into a reactor attached to vac. line, evacuation, transferring of glyme into the reactor, sealing of vessel and placing into an oil bath that is maintained at 65-68°C for 4 days.; Monitoring of react. by fluorine NMR. Spect. anal.;

Reference yield: 18.0%

Bis(trifluoromethyl)disulfid (372-64-5) + mercury → bis(trifluoromethyl)mercury (371-76-6) + mercury bis(trifluoromethanethiolate) (21259-75-6) + CF3Hg(1+)*SCF3(1-)=CF3HgSCF3 (51353-53-8)

Guidance literature:

In neat (no solvent); -196°C, 3 h; distn. in vac.;

Reference yield:

Hg(2+)*((OCH2CH2)7)*2CF3(1-)=(Hg((OCH2CH2)7)(CF3)2) → 1,4,7,10,13,16,10-heptaoxacyclohenicosane (33089-36-0) + bis(trifluoromethyl)mercury (371-76-6)

Guidance literature:

In [⁽²⁾H₆]acetone; benzene-d6; 23°C; Kinetics;

DOI:10.1021/ja00276a054

upstream raw materials:

bis(trifluoromethyl)phenylthallium

Bis(trifluoromethyl)disulfid

Hexafluoroethane

iodotrifluoromethane

Downstream raw materials:

2-(trifluoromethyl)furan

trifluoromethan

2,5-Dihydro-2-trifluormethylfuran

5'-O-tert-butyldimethylsilyl-2',3'-dideoxy-3',4'-C-(difluoromethylene)-β-D-erythro-pentofuranosyl-3-(4-methoxybenzyl)uracil

Refernces

• 1、 Rebek, J.,Luis, S.V.,Marshall, L.R.. "Slow Complexation Rates of Crown Ethers: What Is Taking So Long?". . p. 5011 - 5012. Retrieved 2007/10/02.