9-HYDROXY-3-NITROFLUORENE)

Base Information

Chemical Name:9-HYDROXY-3-NITROFLUORENE)
CAS No.:58084-75-6
Molecular Formula:C13H9 N O3
Molecular Weight:227.219
Hs Code.:
Mol file:58084-75-6.mol

Synonyms:9-Fluorenol,3-nitro- (5CI); NSC 175647

Suppliers and Price of 9-HYDROXY-3-NITROFLUORENE)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 9-HYDROXY-3-NITROFLUORENE)

Chemical Property:

Vapor Pressure:2.98E-09mmHg at 25°C
Boiling Point:459.9°C at 760 mmHg
Flash Point:201.3°C
PSA：66.05000
Density:1.445g/cm³
LogP:3.18010

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 9-HYDROXY-3-NITROFLUORENE)

There total 10 articles about 9-HYDROXY-3-NITROFLUORENE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

: 42135-22-8
3-nitro-9H-fluoren-9-one

: 58084-75-6
9-hydroxy-3-nitrofluorene

: 5397-37-5
3-nitro-9H-fluorene

Guidance literature:: With triethylsilane; In trifluoroacetic acid; for 48h; Ambient temperature;
DOI:10.1055/s-1989-27189

Reference yield:

: 7745-93-9
2-bromo-4-nitrotoluene

: 58084-75-6
9-hydroxy-3-nitrofluorene

Guidance literature:: Multi-step reaction with 7 steps

1: 2.) 2 M aq. Na₂CO₃ / 1.) Pd(PPh₃)4 / 1.) EtOH, DME, 10 min, 2.) reflux, 20 h

2: 76 percent / NBS / benzoyl peroxide / CCl₄ / 36 h / Heating

3: AgNO₃ / dioxane; H₂O / 18 h / Ambient temperature

4: aq. KOH / dioxane / 20 h / Ambient temperature

5: 98 percent / aq. KMnO₄ / acetone / 4 h / Ambient temperature

6: 88 percent / polyphosphoric acid / 5 h / 160 °C

7: 73 percent / Et₃SiH / trifluoroacetic acid / 48 h / Ambient temperature

With triethylsilane; potassium hydroxide; potassium permanganate; N-Bromosuccinimide; PPA; sodium carbonate; silver nitrate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; dibenzoyl peroxide; In 1,4-dioxane; tetrachloromethane; water; acetone; trifluoroacetic acid;
DOI:10.1055/s-1989-27189

Reference yield:

: 13480-38-1
4-Nitro-2-phenyltoluene

: 58084-75-6
9-hydroxy-3-nitrofluorene

Guidance literature:: Multi-step reaction with 6 steps

1: 76 percent / NBS / benzoyl peroxide / CCl₄ / 36 h / Heating

2: AgNO₃ / dioxane; H₂O / 18 h / Ambient temperature

3: aq. KOH / dioxane / 20 h / Ambient temperature

4: 98 percent / aq. KMnO₄ / acetone / 4 h / Ambient temperature

5: 88 percent / polyphosphoric acid / 5 h / 160 °C

6: 73 percent / Et₃SiH / trifluoroacetic acid / 48 h / Ambient temperature

With triethylsilane; potassium hydroxide; potassium permanganate; N-Bromosuccinimide; PPA; silver nitrate; dibenzoyl peroxide; In 1,4-dioxane; tetrachloromethane; water; acetone; trifluoroacetic acid;
DOI:10.1055/s-1989-27189