Technology Process of 9-HYDROXY-3-NITROFLUORENE)
There total 10 articles about 9-HYDROXY-3-NITROFLUORENE) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
triethylsilane;
In
trifluoroacetic acid;
for 48h;
Ambient temperature;
DOI:10.1055/s-1989-27189
- Guidance literature:
-
Multi-step reaction with 7 steps
1: 2.) 2 M aq. Na2CO3 / 1.) Pd(PPh3)4 / 1.) EtOH, DME, 10 min, 2.) reflux, 20 h
2: 76 percent / NBS / benzoyl peroxide / CCl4 / 36 h / Heating
3: AgNO3 / dioxane; H2O / 18 h / Ambient temperature
4: aq. KOH / dioxane / 20 h / Ambient temperature
5: 98 percent / aq. KMnO4 / acetone / 4 h / Ambient temperature
6: 88 percent / polyphosphoric acid / 5 h / 160 °C
7: 73 percent / Et3SiH / trifluoroacetic acid / 48 h / Ambient temperature
With
triethylsilane; potassium hydroxide; potassium permanganate; N-Bromosuccinimide; PPA; sodium carbonate; silver nitrate;
tetrakis(triphenylphosphine) palladium(0); dibenzoyl peroxide;
In
1,4-dioxane; tetrachloromethane; water; acetone; trifluoroacetic acid;
DOI:10.1055/s-1989-27189
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 76 percent / NBS / benzoyl peroxide / CCl4 / 36 h / Heating
2: AgNO3 / dioxane; H2O / 18 h / Ambient temperature
3: aq. KOH / dioxane / 20 h / Ambient temperature
4: 98 percent / aq. KMnO4 / acetone / 4 h / Ambient temperature
5: 88 percent / polyphosphoric acid / 5 h / 160 °C
6: 73 percent / Et3SiH / trifluoroacetic acid / 48 h / Ambient temperature
With
triethylsilane; potassium hydroxide; potassium permanganate; N-Bromosuccinimide; PPA; silver nitrate;
dibenzoyl peroxide;
In
1,4-dioxane; tetrachloromethane; water; acetone; trifluoroacetic acid;
DOI:10.1055/s-1989-27189