triisopropyl(2-((3R,5S)-2-methyl-5-(prop-1-en-2-yl)-3-(prop-2-ynyl)-3-(triethylsilyloxy)cyclohex-1-enyl)ethoxy)silane

Base Information

Chemical Name:triisopropyl(2-((3R,5S)-2-methyl-5-(prop-1-en-2-yl)-3-(prop-2-ynyl)-3-(triethylsilyloxy)cyclohex-1-enyl)ethoxy)silane
CAS No.:1359761-50-4
Molecular Formula:C₃₀H₅₆O₂Si₂
Molecular Weight:504.944
Hs Code.:

Synonyms:triisopropyl(2-((3R,5S)-2-methyl-5-(prop-1-en-2-yl)-3-(prop-2-ynyl)-3-(triethylsilyloxy)cyclohex-1-enyl)ethoxy)silane

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Chemical Property of triisopropyl(2-((3R,5S)-2-methyl-5-(prop-1-en-2-yl)-3-(prop-2-ynyl)-3-(triethylsilyloxy)cyclohex-1-enyl)ethoxy)silane

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Technology Process of triisopropyl(2-((3R,5S)-2-methyl-5-(prop-1-en-2-yl)-3-(prop-2-ynyl)-3-(triethylsilyloxy)cyclohex-1-enyl)ethoxy)silane

There total 6 articles about triisopropyl(2-((3R,5S)-2-methyl-5-(prop-1-en-2-yl)-3-(prop-2-ynyl)-3-(triethylsilyloxy)cyclohex-1-enyl)ethoxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 994-30-9
triethylsilyl chloride

: 1359761-49-1
(1R,5S)-3-(2-(triisopropylsilyloxy)ethyl)-2-methyl-5-(prop-1-en-2-yl)-1-(prop-2-ynyl)cyclohex-2-enol

: 1359761-50-4
triisopropyl(2-((3R,5S)-2-methyl-5-(prop-1-en-2-yl)-3-(prop-2-ynyl)-3-(triethylsilyloxy)cyclohex-1-enyl)ethoxy)silane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 3h;
DOI:10.1021/ol300058t

Reference yield:

: 1359761-47-9
(1S,5R)-1-(2-triisopropylsilyloxyethyl)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enol

: 1359761-50-4
triisopropyl(2-((3R,5S)-2-methyl-5-(prop-1-en-2-yl)-3-(prop-2-ynyl)-3-(triethylsilyloxy)cyclohex-1-enyl)ethoxy)silane

Guidance literature:: Multi-step reaction with 3 steps

1: pyridinium chlorochromate / dichloromethane / 54 h / 23 °C

2: iodine; magnesium; mercury dichloride / diethyl ether; toluene / 20 h / 20 °C / Inert atmosphere

3: 1H-imidazole / N,N-dimethyl-formamide / 3 h / 20 °C

With 1H-imidazole; iodine; magnesium; pyridinium chlorochromate; mercury dichloride; In diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ol300058t

Reference yield:

: 1359761-48-0
(S)-3-(2-triisopropylsilyloxyethyl)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone

: 1359761-50-4
triisopropyl(2-((3R,5S)-2-methyl-5-(prop-1-en-2-yl)-3-(prop-2-ynyl)-3-(triethylsilyloxy)cyclohex-1-enyl)ethoxy)silane

Guidance literature:: Multi-step reaction with 2 steps

1: iodine; magnesium; mercury dichloride / diethyl ether; toluene / 20 h / 20 °C / Inert atmosphere

2: 1H-imidazole / N,N-dimethyl-formamide / 3 h / 20 °C

With 1H-imidazole; iodine; magnesium; mercury dichloride; In diethyl ether; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ol300058t