[(η5-C5(CH3)5)Ru(nitrosyl)(5-phenyl-3-(2-pyridyl)-pyrazolato(1-))](triflate)

Base Information

Chemical Name:[(η5-C5(CH3)5)Ru(nitrosyl)(5-phenyl-3-(2-pyridyl)-pyrazolato(1-))](triflate)
CAS No.:1313480-93-1
Molecular Formula:CF₃O₃S*C₂₄H₂₅N₄ORu
Molecular Weight:635.629
Hs Code.:

Synonyms:[(η5-C5(CH3)5)Ru(nitrosyl)(5-phenyl-3-(2-pyridyl)-pyrazolato(1-))](triflate)

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Chemical Property of [(η5-C5(CH3)5)Ru(nitrosyl)(5-phenyl-3-(2-pyridyl)-pyrazolato(1-))](triflate)

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Technology Process of [(η5-C5(CH3)5)Ru(nitrosyl)(5-phenyl-3-(2-pyridyl)-pyrazolato(1-))](triflate)

There total 3 articles about [(η5-C5(CH3)5)Ru(nitrosyl)(5-phenyl-3-(2-pyridyl)-pyrazolato(1-))](triflate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: [(η5-C5(CH3)5)Ru(nitrosyl)(5-phenyl-3-(2-pyridyl)-1H-pyrazole)](triflate)2*(acetonitrile)

: 1313480-93-1
[(η5-C5(CH3)5)Ru(nitrosyl)(5-phenyl-3-(2-pyridyl)-pyrazolato(1-))](triflate)

Guidance literature:: With K₂CO₃; In dichloromethane; under Ar; mixt. of Ru complex and K2CO3 in CH2Cl2 stirred at room temp. for 17 h; filtered; filtrate evapd. to dryness; recrystd. from MeCN-Et2O;
DOI:10.1246/bcsj.20100331

Reference yield: 74.0%

: [(η5-C5Me5)Ru(NO)Cl2]

: 2926-27-4
potassium trifluoromethansulfonate

: 15395-62-7
2-(5-phenyl-1H-pyrazol-3-yl)-pyridine

: 1313480-93-1
[(η5-C5(CH3)5)Ru(nitrosyl)(5-phenyl-3-(2-pyridyl)-pyrazolato(1-))](triflate)

Guidance literature:: In water; under Ar; mixt. of Ru complex and ligand in H2O stirred at 50°C for 15 h; KSO3CF3 added; stirred at room temp. for 3 h; extd. with CH2Cl2; evapd.; recrystd. from MeCN-Et2O; elem. anal.;
DOI:10.1246/bcsj.20100331

Reference yield: 70.0%

: 7783-99-5
silver(I) nitrite

: [(η5-C5(CH3)5)RuCl(5-phenyl-3-(2-pyridyl)-1H-pyrazole)]*0.5THF

: 2926-27-4
potassium trifluoromethansulfonate

: 1313480-93-1
[(η5-C5(CH3)5)Ru(nitrosyl)(5-phenyl-3-(2-pyridyl)-pyrazolato(1-))](triflate)

Guidance literature:: In acetonitrile; under Ar; mixt. of Ru complex and AgNO2 in MeCN stirred at room temp. for 4 h; filtered; KSO3CF3 added to filtrate; stirred for 3 h; evapd. to dryness; dissolved in CH2Cl2; soln. washed with H2O; solvent removed from sepd. org. layer; elem. anal.;
DOI:10.1246/bcsj.20100331