Nitrous acid;silver

Base Information

• Chemical Name: Nitrous acid;silver
• CAS No.: 7783-99-5
• Molecular Formula: Ag. H N O2
• Molecular Weight: 153.874
• Hs Code.: 28432900
• Mol file: 7783-99-5.mol

Synonyms:

Chemical Property of Nitrous acid;silver

Chemical Property:

• Appearance/Colour: yellow-green powder
• Melting Point: 140 °C(lit.)
• PSA: 52.49000
• Density: 4.453
• LogP: 0.25060
• Sensitive.: Light Sensitive
• Water Solubility.: Soluble in hot water.Insoluble in ethanol.
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 153.90582
• Heavy Atom Count: 4
• Complexity: 13.5

Purity/Quality:

99.9% ^*data from raw suppliers

Silver nitrite, 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn;O;N
• Hazard Codes: O,Xn,N
• Statements: 8-22-36/38-50/53
• Safety Statements: 26-45-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N(=O)O.[Ag]
• Uses: For preparation of standard NaNO2 solution for water analysis; preparation of aliphatic nitro-compounds; as reagent for primary, secondary, and tertiary alcohols. Silver nitrite is used in the silver plating process, hair dye, inks, permanent marker pens and determination of chloride ions in water and drilling fluids. It is used as Tollen?s reagent and used in the formation of aniline and nitro compounds in victor mayer reactions.

Technology Process of Nitrous acid;silver

There total 45 articles about Nitrous acid;silver which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

silver nitrate → silver(I) nitrite (7783-99-5)

Guidance literature:

With Piperonyl butoxide; In solid; grinding a mixture of Pb and AgNO3 at 25°C in a crucible;;

Reference yield:

silver hyponitrite + silver(l) oxide (20667-12-3) → silver(I) nitrite (7783-99-5) + silver (7440-22-4)

Guidance literature:

In neat (no solvent); reaction at 160°C and above;;

DOI:10.1021/ja01624a007

Reference yield:

silver nitrate + sodium nitrite (7632-00-0) → silver(I) nitrite (7783-99-5)

Guidance literature:

NaNO2 purified by recrystn.;

upstream raw materials:

dinitrogen tetraoxide

silver(l) oxide

Nitrogen dioxide

nitric acid

Downstream raw materials:

nitrogen

dinitrogen monoxide

nitrogen(II) oxide

silver

Refernces

• 1、 Hochanadel, G. J.,Dawis, T. W.. "". . p. 333 - 334. Retrieved 1957.
• 2、 Barsanti, Alessandra Caterina,Chiappe, Cinzia,Ghilardi, Tiziana,Pomelli, Christian Silvio. "Functionalized phosphonium based ionic liquids: Properties and application in metal extraction". . p. 38848 - 38854. Retrieved 2014.
• 3、 Kunkely, Horst,Vogler, Arnd. "Excited state properties of silver(I) nitrite complexes: Nitrogen conproportionation in Ag(NH3)NO2 induced by LLCT excitation". . p. 784 - 786. Retrieved 2008/10/09.