(Z)-(2R,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-4,6,8,10,12-pentamethyl-2-oxiranyltridec-8-en-3-ol

Base Information

Chemical Name:(Z)-(2R,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-4,6,8,10,12-pentamethyl-2-oxiranyltridec-8-en-3-ol
CAS No.:1184762-66-0
Molecular Formula:C₄₀H₇₄O₆Si₂
Molecular Weight:707.195
Hs Code.:

Synonyms:(Z)-(2R,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-4,6,8,10,12-pentamethyl-2-oxiranyltridec-8-en-3-ol

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Chemical Property of (Z)-(2R,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-4,6,8,10,12-pentamethyl-2-oxiranyltridec-8-en-3-ol

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Technology Process of (Z)-(2R,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-4,6,8,10,12-pentamethyl-2-oxiranyltridec-8-en-3-ol

There total 1 articles about (Z)-(2R,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-4,6,8,10,12-pentamethyl-2-oxiranyltridec-8-en-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1184762-13-7
(Z)-(3S,4S,5R,6R,7S,11S,12R,13S)-6,12-bis-(tert-butyldimethylsilanyloxy)-14-(4-methoxybenzyloxy)-3,5,7,9,11,13-hexamethyltetradeca-1,9-dien-4-ol

: 1184762-66-0
(Z)-(2R,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-4,6,8,10,12-pentamethyl-2-oxiranyltridec-8-en-3-ol

Guidance literature:: With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; In decane; dichloromethane; at 0 ℃;
DOI:10.1002/anie.200901740

Reference yield: 29.0%

: 1184762-66-0
(Z)-(2R,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-4,6,8,10,12-pentamethyl-2-oxiranyltridec-8-en-3-ol

: 1184762-67-1
(Z)-(2S,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-2,4,6,8,10,12-hexamethyltridec-8-ene-1,3-diol

Guidance literature:: (Z)-(2R,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-4,6,8,10,12-pentamethyl-2-oxiranyltridec-8-en-3-ol; With periodic acid dihydrate; In tetrahydrofuran; diethyl ether; at 0 ℃; for 16h;

With sodium tetrahydroborate; In methanol; at 0 ℃; for 0.5h;
DOI:10.1002/anie.200901740

Reference yield:

: 1184762-66-0
(Z)-(2R,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-4,6,8,10,12-pentamethyl-2-oxiranyltridec-8-en-3-ol

: C₃₉H₇₂O₆Si₂

Guidance literature:: With periodic acid dihydrate; In tetrahydrofuran; diethyl ether; at 0 ℃; for 16h; Inert atmosphere;
DOI:10.1002/chem.200901567