(Z)-(3S,4S,5R,6R,7S,11S,12R,13S)-6,12-bis-(tert-butyldimethylsilanyloxy)-14-(4-methoxybenzyloxy)-3,5,7,9,11,13-hexamethyltetradeca-1,9-dien-4-ol

Base Information

Chemical Name:(Z)-(3S,4S,5R,6R,7S,11S,12R,13S)-6,12-bis-(tert-butyldimethylsilanyloxy)-14-(4-methoxybenzyloxy)-3,5,7,9,11,13-hexamethyltetradeca-1,9-dien-4-ol
CAS No.:1184762-13-7
Molecular Formula:C₄₀H₇₄O₅Si₂
Molecular Weight:691.196
Hs Code.:

Synonyms:(Z)-(3S,4S,5R,6R,7S,11S,12R,13S)-6,12-bis-(tert-butyldimethylsilanyloxy)-14-(4-methoxybenzyloxy)-3,5,7,9,11,13-hexamethyltetradeca-1,9-dien-4-ol

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Chemical Property of (Z)-(3S,4S,5R,6R,7S,11S,12R,13S)-6,12-bis-(tert-butyldimethylsilanyloxy)-14-(4-methoxybenzyloxy)-3,5,7,9,11,13-hexamethyltetradeca-1,9-dien-4-ol

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Technology Process of (Z)-(3S,4S,5R,6R,7S,11S,12R,13S)-6,12-bis-(tert-butyldimethylsilanyloxy)-14-(4-methoxybenzyloxy)-3,5,7,9,11,13-hexamethyltetradeca-1,9-dien-4-ol

There total 2 articles about (Z)-(3S,4S,5R,6R,7S,11S,12R,13S)-6,12-bis-(tert-butyldimethylsilanyloxy)-14-(4-methoxybenzyloxy)-3,5,7,9,11,13-hexamethyltetradeca-1,9-dien-4-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₆H₆₆O₅Si₂

: 99687-40-8,106357-20-4,106357-33-9,99745-86-5
(R,R)-[(E)-2-butenyl]diisopropyl tartrate boronate

: 1184762-13-7
(Z)-(3S,4S,5R,6R,7S,11S,12R,13S)-6,12-bis-(tert-butyldimethylsilanyloxy)-14-(4-methoxybenzyloxy)-3,5,7,9,11,13-hexamethyltetradeca-1,9-dien-4-ol

Guidance literature:: C₃₆H₆₆O₅Si₂; (R,R)-[(E)-2-butenyl]diisopropyl tartrate boronate; In toluene; at -78 ℃;

With sodium hydroxide; In water; toluene; at 0 ℃; for 0.75h;
DOI:10.1002/anie.200901740

Reference yield:

: C₃₆H₆₆O₅Si₂

: (R,R)-diisopropyl tartrate (E)-crotylborate

: 1184762-13-7
(Z)-(3S,4S,5R,6R,7S,11S,12R,13S)-6,12-bis-(tert-butyldimethylsilanyloxy)-14-(4-methoxybenzyloxy)-3,5,7,9,11,13-hexamethyltetradeca-1,9-dien-4-ol

Guidance literature:: In toluene; at -78 ℃; Inert atmosphere;
DOI:10.1002/chem.200901567

Reference yield: 87.0%

: 1184762-13-7
(Z)-(3S,4S,5R,6R,7S,11S,12R,13S)-6,12-bis-(tert-butyldimethylsilanyloxy)-14-(4-methoxybenzyloxy)-3,5,7,9,11,13-hexamethyltetradeca-1,9-dien-4-ol

: 1184762-66-0
(Z)-(2R,3S,4R,5R,6S,10S,11R,12S)-5,11-bis-(tert-butyldimethylsilanyloxy)-13-(4-methoxybenzyloxy)-4,6,8,10,12-pentamethyl-2-oxiranyltridec-8-en-3-ol

Guidance literature:: With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; In decane; dichloromethane; at 0 ℃;
DOI:10.1002/anie.200901740