[2-(2-Methoxy-ethoxymethoxy)-1-pentadecyl-cyclopropanesulfonyl]-benzene

Base Information

• Chemical Name: [2-(2-Methoxy-ethoxymethoxy)-1-pentadecyl-cyclopropanesulfonyl]-benzene
• CAS No.: 100905-01-9
• Molecular Formula: C₂₈H₄₈O₅S
• Molecular Weight: 496.752
• Mol file: 100905-01-9.mol

Synonyms:[2-(2-Methoxy-ethoxymethoxy)-1-pentadecyl-cyclopropanesulfonyl]-benzene

Chemical Property of [2-(2-Methoxy-ethoxymethoxy)-1-pentadecyl-cyclopropanesulfonyl]-benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2-(2-Methoxy-ethoxymethoxy)-1-pentadecyl-cyclopropanesulfonyl]-benzene

There total 2 articles about [2-(2-Methoxy-ethoxymethoxy)-1-pentadecyl-cyclopropanesulfonyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

pentadecyl bromide (629-72-1) + 1-<(2-methoxyethoxy)methoxy>-2-phenylsulfonyl-cyclopropane (100904-90-3) → [2-(2-Methoxy-ethoxymethoxy)-1-pentadecyl-cyclopropanesulfonyl]-benzene (100905-01-9)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃;

DOI:10.1016/S0040-4039(00)89204-7

Reference yield:

1-<(2-methoxyethoxy)methoxy>-2-(phenylthio)cyclopropane (84547-20-6) → [2-(2-Methoxy-ethoxymethoxy)-1-pentadecyl-cyclopropanesulfonyl]-benzene (100905-01-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 80 percent / m-chloroperbenzoic acid / CH₂Cl₂

2: 73 percent / lithium diisopropylamide, hexamethylphosphortriamide / tetrahydrofuran / -78 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;

DOI:10.1016/S0040-4039(00)89204-7

Reference yield:

[2-(2-Methoxy-ethoxymethoxy)-1-pentadecyl-cyclopropanesulfonyl]-benzene (100905-01-9) → (E)-octadec-2-enal (51534-37-3)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrafluoroboric acid (50percent) / CH₂Cl₂; H₂O / 7 h / Heating

2: 90 percent / NaHCO₃ / tetrahydrofuran; H₂O / 4 h / Heating

With tetrafluoroboric acid; sodium hydrogencarbonate; In tetrahydrofuran; dichloromethane; water;

DOI:10.1016/S0040-4039(00)89204-7

upstream raw materials:

pentadecyl bromide

1-<(2-methoxyethoxy)methoxy>-2-phenylsulfonyl-cyclopropane

1-<(2-methoxyethoxy)methoxy>-2-(phenylthio)cyclopropane

Downstream raw materials:

2-Benzenesulfonyl-2-pentadecyl-cyclopropanol

(E)-octadec-2-enal