propyl 3-nitrobenzoate

Base Information

• Chemical Name: propyl 3-nitrobenzoate
• CAS No.: 59265-70-2
• Molecular Formula: C₁₀H₁₁NO₄
• Molecular Weight: 209.202
• Mol file: 59265-70-2.mol

Synonyms:propyl 3-nitrobenzoate

Chemical Property of propyl 3-nitrobenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of propyl 3-nitrobenzoate

There total 9 articles about propyl 3-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

propan-1-ol (71-23-8) + 3-nitro-benzaldehyde (99-61-6) → propyl 3-nitrobenzoate (59265-70-2)

Guidance literature:

With dibromamine-T; potassium carbonate; In acetonitrile; at 20 ℃; for 2h;

DOI:10.1016/j.tetlet.2014.07.124

Reference yield: 78.0%

propyl bromide (106-94-5) + 3-nitrobenzoic acid (121-92-6) → propyl 3-nitrobenzoate (59265-70-2)

Guidance literature:

With 3,3'-(2,2'-(hexane-1,6-diylbis(azanediyl))bis(2-oxoethane-2,1-diyl))bis(1-propyl-1H-benzo[d]imidazol-3-ium) chloride; triethylamine; at 60 ℃; for 0.416667h;

DOI:10.1016/j.apcata.2014.06.004

Reference yield: 74.0%

propan-1-ol (71-23-8) + (3-nitrophenyl)acetonitrile (621-50-1) → propyl 3-nitrobenzoate (59265-70-2)

Guidance literature:

With iodine; oxygen; potassium iodide; at 20 ℃; for 72h;

DOI:10.3184/030823407X218110

upstream raw materials:

m-nitrobenzyl n-propyl ether

α-hydroperoxy-m-nitrobenzyl n-propyl ether

propan-1-ol

3-nitrobenzoic acid

Downstream raw materials:

3-(3-Methyl-ureido)-benzoic acid propyl ester

3-n-Propoxycarbonylphenylisocyanat

n-propyl 3-aminobenzoate

Refernces

• 1、 Sarma, Manas Jyoti,Phukan, Prodeep. "Formation of esters and amides via metal-free Csp2-Csp3 bond cleavage of α-nitro ketone: Mechanistic insight to the reaction pathway". . p. 523 - 533. Retrieved 2019/05/21.
• 2、 Muskawar, Prashant Narayan,Thenmozhi,Gajbhiye, Jayant M.,Bhagat, Pundlik Rambhau. "Facile esterification of carboxylic acid using amide functionalized benzimidazolium dicationic ionic liquids". . p. 214 - 220. Retrieved 2014/07/08.